Synthesis of Fluorine-Containing Aryl(halo)boranes from Potassium Aryl(fluoro)borates

Synthesis of Fluorine-Containing Aryl(halo)boranes from Potassium Aryl(fluoro)borates Научная публикация

Журнал

Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350

Вых. Данные

Год: 2020, Том: 90, Номер: 1, Страницы: 50-61 Страниц : 12 DOI: 10.1134/S1070363220010089

Авторы

Bardin V.V. ¹ , Prikhod’ko S.A. ² , Shmakov M.M. ² , Shabalin A.Y. ² , Adonin N.Y. ²

Организации

1	N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, 630090 Russia
2	Federal Research Center “G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences,” Novosibirsk, 630090 Russia

Fluorine-containing aryldihalogenoboranes have been obtained by the reaction of boron and aluminum chlorides and bromides with potassium aryltrifluoroborates K[ArBF3] under mild conditions. In a similar way, bis(pentafluorophenyl)halogenoboranes have been synthesized by the reaction with K[(C6F5)2BF2]. The reaction of K[C6F5BF3] with AlBr3 affords a mixture of C6F5BF2 and C6F5BCl2 due to fast conversion of AlBr3 to AlBrCl2. The inductive and resonance parameters of BCl2 and BBr2 groups were calculated. © 2020, Pleiades Publishing, Ltd.

Bardin V.V. , Prikhod’ko S.A. , Shmakov M.M. , Shabalin A.Y. , Adonin N.Y.
Synthesis of Fluorine-Containing Aryl(halo)boranes from Potassium Aryl(fluoro)borates
Russian Journal of General Chemistry. 2020. V.90. N1. P.50-61. DOI: 10.1134/S1070363220010089 WOS Scopus РИНЦ CAPlus OpenAlex Sciact

Поступила в редакцию:	13 июн. 2019 г.
Принята к публикации:	20 июн. 2019 г.
Опубликована в печати:	1 янв. 2020 г.
Опубликована online:	26 мар. 2020 г.

Web of science:	WOS:000521739700008
Scopus:	2-s2.0-85082666616
РИНЦ:	43263503
Chemical Abstracts:	2020:587772
OpenAlex:	W3013115111
Sciact:	35115

БД	Цитирований
OpenAlex	3