Metal-carbon nanocomposite systems as stable and active catalysts for chlorobenzene transformations

Metal-carbon nanocomposite systems as stable and active catalysts for chlorobenzene transformations Научная публикация

Конференция

10th International Symposium on the Scientific Bases for the Preparation of Heterogeneous Catalysts
11-15 июл. 2010 , Louvain-la-Neuve

Сборник

Scientific Bases for the Preparation of Heterogeneous Catalysts : Proceedings of the 10th International Symposium, Louvain-la-Neuve, Belgium, July 11-15, 2010
Сборник, Elsevier. Amsterdam, The Netherlands.2010. 857 c. ISBN 9780444536013.

Журнал

Studies in Surface Science and Catalysis
ISSN: 0167-2991

Вых. Данные

Год: 2010, Том: 175, Страницы: 289-292 Страниц : 4 DOI: 10.1016/s0167-2991(10)75044-8

Авторы

Lokteva Ekaterina ¹ , Erokhin Alexey ¹ , Kachevsky Stanislav ¹ , Yermakov Anatoly ² , Uimin Mikhail ² , Mysik Aleksey ² , Golubina Elena ¹ , Zanaveskin Konstantin ³ , Turakulova Anara ¹ , Lunin Valery ¹

Организации

1	Lomonosov Moscow State University
2	M.N. Mikheev Institute of Metal Physics of the Ural Branch of the Russian Academy of Sciences (IMP UB RAS)
3	Karpov Institute of Physical Chemistry

Nanocomposites based on Pd and Ni encapsulated (@) in carbon have been prepared by condensation of nanoparticles in the flow of gas mixture (Ar and hydrocarbons) and characterized by TEM, TGA-MS, XRD spectroscopy and BET adsorption measurements. Ni@C, NiPd@C nanocomposites consist of metal core 3-10 nm in size covered by a few carbon layers; Pd particles are 10-15 nm in size, have no carbon shell and are joined in chains. Catalytic properties were investigated in hydrodechlorination (HDC) of chlorobenzene in gas phase and 1,2,4-trichlorobenzene in liquid phase. Totally carbon covered particles of Ni and Pd-Ni demonstrate high activity and stability in gas-phase hydrodechlorination of chlorobenzene at 100-350 degrees C and in liquid phase HDC of 1,2,4-trichlorobenzene at 130 degrees C under middle pressure.

Lokteva E. , Erokhin A. , Kachevsky S. , Yermakov A. , Uimin M. , Mysik A. , Golubina E. , Zanaveskin K. , Turakulova A. , Lunin V.
Metal-carbon nanocomposite systems as stable and active catalysts for chlorobenzene transformations
В сборнике Scientific Bases for the Preparation of Heterogeneous Catalysts : Proceedings of the 10th International Symposium, Louvain-la-Neuve, Belgium, July 11-15, 2010. – Elsevier., 2010. – C.289-292. – ISBN 9780444536013. DOI: 10.1016/s0167-2991(10)75044-8 Scopus OpenAlex

Scopus:	2-s2.0-79551649950
OpenAlex:	W1495886735

БД	Цитирований
OpenAlex	2