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Co- and Fe-containing Silica-based Catalysts Synthesized in Subcritical Water Научная публикация

Журнал Chemical Engineering Transactions
ISSN: 1974-9791
Вых. Данные Год: 2019, Том: 74, Страницы: 469-474 Страниц : 6 DOI: 10.3303/cet1974079
Авторы Stepacheva Antonina 1 , Markova Mariia 2 , Gavrilenko Alexandra 1 , Sidorov Alexander 1 , Kosivtsov Yury 1 , Sulman Esther 1
Организации
1 Tver State Technical University
2 Тверской государственный университет
Реферат: A study of the structure and catalytic properties of the cobalt- and iron-containing catalysts synthesized by the subcritical deposition in the water medium was performed in the current work. The catalyst synthesis was carried out at a temperature of 200 °C and a total pressure of 7.5 MPa using silica as support. The catalytic activity of the synthesized materials was studied in the liquid-phase Fischer-Tropsch synthesis. The study of catalyst structure and composition showed that the use of silica as catalyst support allows the formation of Co- and Fe-containing particles consisted of metal oxides. Testing of the synthesized catalysts in liquid phase Fischer-Tropsch synthesis showed that Co-based catalyst allowed the formation of gasoline-range hydrocarbons. It is noteworthy that Co/SiO2 showed higher selectivity towards the formation of linear C5-C8 hydrocarbons. In the case of Fe-containing catalyst, the formation of a significant amount of oxygenates (C3-C4 alcohols) was found.
Библиографическая ссылка: Stepacheva A. , Markova M. , Gavrilenko A. , Sidorov A. , Kosivtsov Y. , Sulman E.
Co- and Fe-containing Silica-based Catalysts Synthesized in Subcritical Water
Chemical Engineering Transactions. 2019. V.74. P.469-474. DOI: 10.3303/cet1974079 Scopus РИНЦ OpenAlex
Идентификаторы БД:
Scopus: 2-s2.0-85067074927
РИНЦ: 41630335
OpenAlex: W3046508216
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БД Цитирований
OpenAlex 1
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