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Magnetically recoverable catalysts for the conversion of inulin to mannitol Научная публикация

Журнал Energy
ISSN: 0360-5442
Вых. Данные Год: 2018, Том: 154, Страницы: 1-6 Страниц : 6 DOI: 10.1016/j.energy.2018.04.103
Авторы Manaenkov Oleg V. 1 , Ratkevich Ekaterina A. 1 , Kislitsa Olga V. 1 , Lawson Bret 2 , Morgan David Gene 2 , Stepacheva Antonina A. 1 , Matveeva Valentina G. 1 , Sulman Mikhail G. 1 , Sulman Esther M. 1 , Bronstein Lyudmila M. 3,2,4
Организации
1 Tver State Technical University, A. Nikitin str. 22, 170026, Tver, Russia
2 Indiana University, Department of Chemistry, Bloomington, IN 47405, USA
3 A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Vavilova St. 28, Moscow, Russia
4 King Abdulaziz University, Faculty of Science, Department of Physics, Jeddah, Saudi Arabia
Реферат: Inulin is a naturally occurring polysaccharide, widely available as plant biomass. Here, we report utilization of a magnetically separable Ru-containing catalyst based on magnetic silica (Fe3O4-SiO2) in the inulin hydrolytic hydrogenation to mannitol (a sweetener used in diabetic foods). The influence of the reaction parameters on the selectivity to mannitol has been studied. Under the optimal conditions the maximum selectivity to mannitol reached 44.3% at 100% conversion of the initial polysaccharide, exceeding that obtained with conventional Ru/C. The catalyst used in this work is stable under hydrothermal conditions of the process. It can be easily magnetically separated from the reaction mixture and reused without any loss of selectivity and activity, making this catalyst promising for practical applications in biomass conversion.
Библиографическая ссылка: Manaenkov O.V. , Ratkevich E.A. , Kislitsa O.V. , Lawson B. , Morgan D.G. , Stepacheva A.A. , Matveeva V.G. , Sulman M.G. , Sulman E.M. , Bronstein L.M.
Magnetically recoverable catalysts for the conversion of inulin to mannitol
Energy. 2018. V.154. P.1-6. DOI: 10.1016/j.energy.2018.04.103 Scopus РИНЦ OpenAlex
Идентификаторы БД:
Scopus: 2-s2.0-85047407554
РИНЦ: 35526811
OpenAlex: W2801863092
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