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Manganese Oxide Nanoparticles Immobilized on Silica Nanospheres as a Highly Efficient Catalyst for Heavy Oil Oxidation Научная публикация

Журнал Industrial & Engineering Chemistry Research
ISSN: 0888-5885 , E-ISSN: 1520-5045
Вых. Данные Год: 2019, Том: 58, Номер: 21, Страницы: 8990-8995 Страниц : 6 DOI: 10.1021/acs.iecr.9b00080
Авторы Galukhin Andrey 1 , Nosov Roman 1 , Eskin Alexey 1 , Khelkhal Mohammed 1 , Osin Yuri 1
Организации
1 Kazan Federal University, 18 Kremlevskaya str., Kazan 420008, Russian Federation
Реферат: Nanoparticles have proven to be successful catalysts for oil combustion. To maximize their catalytic performance, it is necessary to provide nanoparticle aggregation stability during the combustion process. The classical approach to stabilization of nanoparticles assumes application of different stabilizers, like surfactants or polymers, attached to particles’ surfaces, preventing their aggregation via steric or electrostatic repulsion. Thus, the aggregation stability of nanoparticles is determined by the thermal stability of the surfactant- or polymer-based coatings, which is not sufficient for high-temperature processes. In the current study we prepared a catalyst with high thermal stability by immobilization of 10 nm sized MnOx nanoparticles on a surface of 70 nm silica nanospheres. The composition, morphological, and textural parameters of the catalyst were optimized via variation of synthetic conditions. The high catalytic performance of the obtained nanoparticles in heavy oil combustion was proven by evaluation of kinetic parameters of catalytic and noncatalytic processes.
Библиографическая ссылка: Galukhin A. , Nosov R. , Eskin A. , Khelkhal M. , Osin Y.
Manganese Oxide Nanoparticles Immobilized on Silica Nanospheres as a Highly Efficient Catalyst for Heavy Oil Oxidation
Industrial & Engineering Chemistry Research. 2019. V.58. N21. P.8990-8995. DOI: 10.1021/acs.iecr.9b00080 Scopus OpenAlex
Идентификаторы БД:
Scopus: 2-s2.0-85066425228
OpenAlex: W2943834577
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OpenAlex 31
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