Diphenylacetylene hydrogenation on a PdAg /Al 2 O 3 single-atom catalyst: an experimental and DFT study

Diphenylacetylene hydrogenation on a PdAg /Al 2 O 3 single-atom catalyst: an experimental and DFT study Краткое сообщение

Журнал

Mendeleev Communications
ISSN: 0959-9436

Вых. Данные

Год: 2017, Том: 27, Номер: 6, Страницы: 615-617 Страниц : 3 DOI: 10.1016/j.mencom.2017.11.026

Авторы

Rassolov Aleksandr V. ¹ , Krivoruchenko Dmitry S. ¹ , Medvedev Michael G. ¹ , Mashkovsky Igor S. ¹ , Stakheev Aleksandr Yu. ¹ , Svitanko Igor V. ¹

Организации

1	N.D. Zelinsky Institute of Organic Chemistry RAS

The hydrogenation of diphenylacetylene (DPA) on palladium–silver catalysts with a single-atom structure was investigated. It has been shown experimentally that the reaction rate of alkene to alkane hydrogenation is substantially lower than the rate of DPA semi-hydrogenation. The kinetic barriers of all stages of hydrogenation were calculated by the DFT method.

Rassolov A.V. , Krivoruchenko D.S. , Medvedev M.G. , Mashkovsky I.S. , Stakheev A.Y. , Svitanko I.V.
Diphenylacetylene hydrogenation on a PdAg /Al 2 O 3 single-atom catalyst: an experimental and DFT study
Mendeleev Communications. 2017. V.27. N6. P.615-617. DOI: 10.1016/j.mencom.2017.11.026 WOS Scopus OpenAlex

Web of science:	WOS:000418983900026
Scopus:	2-s2.0-85034835343
OpenAlex:	W2769826061

БД	Цитирований
OpenAlex	19