X-Ray Absorption Spectroscopy Study of ZnO-CuO-HPS Catalyst Научная публикация
| Журнал |
Chemical Engineering Transactions
ISSN: 1974-9791 |
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| Вых. Данные | Год: 2017, Том: 61, Страницы: 607-612 Страниц : 6 DOI: 10.3303/cet1761099 | ||||
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Реферат:
The current paper reports the X-Ray Absorption Spectroscopy (XAS) study of novel ZnO-CuO based on hypercrosslinked polystyrene (HPS) catalyst for liquid phase methanol synthesis. It was shown that for the initial catalyst both Cu and Zn exist in the 2+ electronic states. The reduction treatment leads to the change of the Cu electronic state to +1. It should be noted that after the reaction the electronic state of Cu does not change. The synthesized catalyst allows reaching methanol (MeOH) formation up to 2,300 mg-MeOH·kg-cat-1·h-1 under the chosen reaction conditions while methane (Me) formation decreases down to 60 mg-Me·kg-cat-1·h-1.
Библиографическая ссылка:
Sidorov A.I.
, Tkachenko O.P.
, Sulman E.M.
, Doluda V.Y.
, Stepacheva A.A.
X-Ray Absorption Spectroscopy Study of ZnO-CuO-HPS Catalyst
Chemical Engineering Transactions. 2017. V.61. P.607-612. DOI: 10.3303/cet1761099 Scopus РИНЦ OpenAlex
X-Ray Absorption Spectroscopy Study of ZnO-CuO-HPS Catalyst
Chemical Engineering Transactions. 2017. V.61. P.607-612. DOI: 10.3303/cet1761099 Scopus РИНЦ OpenAlex
Идентификаторы БД:
| Scopus: | 2-s2.0-85030748737 |
| РИНЦ: | 31091153 |
| OpenAlex: | W4387715147 |