Adsorption Processes for the Synthesis of Catalytically Active Metal Nanoparticles in Polymeric Matrices

Adsorption Processes for the Synthesis of Catalytically Active Metal Nanoparticles in Polymeric Matrices Научная публикация

Конференция

CHISA : 21st International Congress of Chemical and Process Engineering
23-27 авг. 2014 , Prague

Журнал

Chemical Engineering and Technology
ISSN: 0930-7516 , E-ISSN: 1521-4125

Вых. Данные

Год: 2015, Том: 38, Номер: 4, Страницы: 683-689 Страниц : 7 DOI: 10.1002/ceat.201400631

Авторы

Sulman Esther , Sulman Mikhail , Tyamina Irina , Doluda Valentin , Nikoshvili Linda , Lyubimova Nadezhda , Sidorov Alexander , Matveeva Valentina

Организации

1	Tver State Technical University

The influence of the content of a hydrophilic Pd(II) compound (disodium tetrachloropalladate, Na2PdCl4) on its adsorption and nanoparticle (NP) formation in the pores of hydrophobic micro/mesoporous hypercrosslinked polystyrene (HPS) was systematically investigated. The morphology and composition of HPS-Pd nanocomposites were studied using transmission electron microscopy, X-ray fluorescence measurements, and liquid nitrogen physisorption. The size of Pd-containing NP was found to depend on the content of the hydrophilic Pd(II) compound. Catalytic testing of these nanocomposites in the partial hydrogenation of acetylene alcohols was carried out to illustrate the influence of the NP size on the catalytic activity. The highest catalytic activity was achieved for HPS/Pd-0.1 %, forming small NP.

Sulman E. , Sulman M. , Tyamina I. , Doluda V. , Nikoshvili L. , Lyubimova N. , Sidorov A. , Matveeva V.
Adsorption Processes for the Synthesis of Catalytically Active Metal Nanoparticles in Polymeric Matrices
Chemical Engineering and Technology. 2015. V.38. N4. P.683-689. DOI: 10.1002/ceat.201400631 Scopus OpenAlex

Scopus:	2-s2.0-84925347836
OpenAlex:	W2145587844

БД	Цитирований
OpenAlex	4