Paramagnetic complexes of monovalent and trivalent nickel in the catalytic system Ni(COD)2/BF3∙OEt2 active in norbornene polymerization Научная публикация
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Catalysis Communications
ISSN: 1566-7367 |
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| Вых. Данные | Год: 2010, Том: 12, Номер: 7, Страницы: 634-636 Страниц : 3 DOI: 10.1016/j.catcom.2010.12.016 | ||
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Реферат:
It has been shown that the system Ni(COD)2/BF3∙ OEt2 may polymerize norbornene with the activity of 1930 kg NB/molNi h. This catalytic system is characterized by minor content of the Lewis acid; the activity peaks at the molar ratio of B:Ni = 5. The norbornene polymerization was first demonstrated to be attended with the formation of trivalent nickel metallocyclic complexes. A monovalent nickel complex was used as a precursor for the active species.
Библиографическая ссылка:
Kraikivskii P.B.
, Saraev V.V.
, Bocharova V.V.
, Matveev D.A.
, Petrovskii S.K.
, Gotsko M.D.
Paramagnetic complexes of monovalent and trivalent nickel in the catalytic system Ni(COD)2/BF3∙OEt2 active in norbornene polymerization
Catalysis Communications. 2010. V.12. N7. P.634-636. DOI: 10.1016/j.catcom.2010.12.016 WOS Scopus РИНЦ OpenAlex
Paramagnetic complexes of monovalent and trivalent nickel in the catalytic system Ni(COD)2/BF3∙OEt2 active in norbornene polymerization
Catalysis Communications. 2010. V.12. N7. P.634-636. DOI: 10.1016/j.catcom.2010.12.016 WOS Scopus РИНЦ OpenAlex
Идентификаторы БД:
| Web of science: | WOS:000287839600015 |
| Scopus: | 2-s2.0-78651099218 |
| РИНЦ: | 16683371 |
| OpenAlex: | W2044600687 |