Formation of the paramagletic Ni(I) π-allyl complex in the Ni(allyl)2 – (2,6-diisopropylphenyl)diazabutadiene system Научная публикация
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Journal of Organometallic Chemistry
ISSN: 0022-328X |
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| Вых. Данные | Год: 2011, Том: 696, Номер: 22, Страницы: 3483-3490 Страниц : 8 DOI: 10.1016/j.jorganchem.2011.07.023 | ||||
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Реферат:
It has been shown that the reaction of Ni(allyl)2 with (2,6-diisopropylphenyl)diazabutadiene gives the imino-amide Ni complex (1). The imino-amide moiety of this complex undergoes some complicated rearrangements resulting in spontaneous formation of a paramagnetic π-allyl Ni(I) complex. Nickel complexes formed in the system have been studied with ESR, FTIR, 2D NMR, and mass spectrometry. The structure of complex 1 was studied with X-ray diffraction.
Библиографическая ссылка:
Kraikivskii P.B.
, Saraev V.V.
, Bocharova V.V.
, Romanenko G.V.
, Petrovskii S.K.
, Matveev D.A.
Formation of the paramagletic Ni(I) π-allyl complex in the Ni(allyl)2 – (2,6-diisopropylphenyl)diazabutadiene system
Journal of Organometallic Chemistry. 2011. V.696. N22. P.3483-3490. DOI: 10.1016/j.jorganchem.2011.07.023 WOS Scopus РИНЦ OpenAlex
Formation of the paramagletic Ni(I) π-allyl complex in the Ni(allyl)2 – (2,6-diisopropylphenyl)diazabutadiene system
Journal of Organometallic Chemistry. 2011. V.696. N22. P.3483-3490. DOI: 10.1016/j.jorganchem.2011.07.023 WOS Scopus РИНЦ OpenAlex
Идентификаторы БД:
| Web of science: | WOS:000295717300005 |
| Scopus: | 2-s2.0-80052964274 |
| РИНЦ: | 18006259 |
| OpenAlex: | W2045447766 |