2D-NMR and EPR study of the activation of π-allyl group within the coordination sphere of the imine–amide complex of nickel(II) by the coordination of PMe Научная публикация
| Журнал |
Journal of Organometallic Chemistry
ISSN: 0022-328X |
||||||
|---|---|---|---|---|---|---|---|
| Вых. Данные | Год: 2012, Том: 715, Страницы: 43-47 Страниц : 5 DOI: 10.1016/j.jorganchem.2012.05.035 | ||||||
| Авторы |
|
||||||
| Организации |
|
Реферат:
It has been shown that the coordination of a tertiary phosphine to the π-allyl imine–amide complex of nickel(II) affects the nickel oxidation state and leads to the irreversible elimination of the allyl group in the form of a cyclodimerization product. The coordination of PMe3 to allyl imine–amide complex 1 brings about the formation of phosphine allyl imine–amide complex of nickel(II) 3. In solution it spontaneously disproportionates giving nickel(I) complex 4 and cyclohexene. The isolated nickel complexes are X-ray amorphous, so they have been thoroughly studied with EPR and 2D-NMR spectroscopy.
Библиографическая ссылка:
Kraikivskii P.B.
, Saraev V.V.
, Meusinger R.
, Bocharova V.V.
, Ushakov I.A.
, Petrovskii S.K.
2D-NMR and EPR study of the activation of π-allyl group within the coordination sphere of the imine–amide complex of nickel(II) by the coordination of PMe
Journal of Organometallic Chemistry. 2012. V.715. P.43-47. DOI: 10.1016/j.jorganchem.2012.05.035 WOS Scopus РИНЦ OpenAlex
2D-NMR and EPR study of the activation of π-allyl group within the coordination sphere of the imine–amide complex of nickel(II) by the coordination of PMe
Journal of Organometallic Chemistry. 2012. V.715. P.43-47. DOI: 10.1016/j.jorganchem.2012.05.035 WOS Scopus РИНЦ OpenAlex
Идентификаторы БД:
| Web of science: | WOS:000306422500009 |
| Scopus: | 2-s2.0-84863981340 |
| РИНЦ: | 20477462 |
| OpenAlex: | W2171972883 |