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Palladium catalysed hydroxycarbonylation of 1-phenylethanol in molten salt media Научная публикация

Журнал Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169
Вых. Данные Год: 2006, Том: 252, Номер: 1-2, Страницы: 245-251 Страниц : 7 DOI: 10.1016/j.molcata.2006.02.061
Авторы Lapidus Albert , Eliseev Oleg , Bondarenko Tatyana , Stepin Nikolaj
Организации
1 N.D. Zelinsky Institute of Organic Chemistry RAS
Реферат: Hydroxycarbonylation of 1-phenylethanol (PE) in molten salt media was studied systematically. Phosphine-free palladium catalysts are active in bromide-containing molten salts such as tetrabutylammonium bromide and [BMIM][Br]. The nature of the anion, CO pressure and the presence of PPh3 affect the reaction rate and selectivity. A two-route reaction scheme is proposed to explain the regularities of the process. The catalytic system can be used repeatedly by simple extraction of products with diethyl ether. Nine cycles were carried out without loss of activity.
Библиографическая ссылка: Lapidus A. , Eliseev O. , Bondarenko T. , Stepin N.
Palladium catalysed hydroxycarbonylation of 1-phenylethanol in molten salt media
Journal of Molecular Catalysis A: Chemical. 2006. V.252. N1-2. P.245-251. DOI: 10.1016/j.molcata.2006.02.061 WOS Scopus РИНЦ OpenAlex
Идентификаторы БД:
Web of science: WOS:000237695400038
Scopus: 2-s2.0-33748057828
РИНЦ: 13532275
OpenAlex: W1997301057
Цитирование в БД:
БД Цитирований
OpenAlex 27
Scopus 30
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