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Determination of Conditions for the Technologically Optimized Reduction of Highly Efficient Fischer–Tropsch Synthesis Catalysts Научная публикация

Журнал Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555
Вых. Данные Год: 2025, Том: 17, Номер: 1, Страницы: 10–20 Страниц : DOI: 10.1134/S2070050424700351
Авторы Solomonik I.G. 1 , Mordkovich V.Z. 1
Организации
1 Technological Institute for Superhard and Novel Carbon Materials, Kurchatov Institute National Research Centre, Moscow, 123098 Russia
Реферат: The activation of highly efficient cobalt catalysts for Fischer–Tropsch synthesis has been studied taking into account the transformation of the resulting structures and the presence of a heat-conducting percolation network of metallic aluminum. The effect of the temperature, process duration, reducing gas composition, and reducing gas hourly space velocity on the degree of reduction and the specific surface area of the active catalyst component has been studied. The above characteristics have been determined by low- and high-temperature oxygen titration on a chromatographic sorption unit and by temperature-programmed reduction. The tests have shown the possibility of decreasing the temperature and the hydrogen concentration in the gas to achieve the required parameters during reduction to synthesize a highly efficient catalyst system. The parameters of this system in Fischer–Tropsch synthesis (CO conversion, liquid hydrocarbon productivity) are comparable to or better than for a catalyst reduced under standard conditions.
Библиографическая ссылка: Solomonik I.G. , Mordkovich V.Z.
Determination of Conditions for the Technologically Optimized Reduction of Highly Efficient Fischer–Tropsch Synthesis Catalysts
Catalysis in Industry. 2025. V.17. N1. P.10–20. DOI: 10.1134/S2070050424700351 WOS Scopus РИНЦ OpenAlex
Оригинальная версия: Соломоник И.Г. , Мордкович В.З.
Определение условий технологически оптимизированного восстановления высокопроизводительных катализаторов синтеза Фишера–Тропша
Катализ в промышленности. 2024. №3. С.60-70. DOI: 10.18412/1816-0387-2024-3-60-70 РИНЦ CAPlus OpenAlex
Даты:
Поступила в редакцию: 22 нояб. 2023 г.
Принята к публикации: 15 янв. 2024 г.
Опубликована online: 23 мая 2025 г.
Идентификаторы БД:
Web of science: WOS:001494376100005
Scopus: 2-s2.0-105006694662
РИНЦ: 82358109
OpenAlex: W4410696660
Альметрики: