Novel dicarboxylate heteroaromatic metal organic frameworks as the catalyst supports for the hydrogenation reaction

Novel dicarboxylate heteroaromatic metal organic frameworks as the catalyst supports for the hydrogenation reaction Научная публикация

Конференция

10th International Symposium on the Scientific Bases for the Preparation of Heterogeneous Catalysts
11-15 июл. 2010 , Louvain-la-Neuve

Журнал

Studies in Surface Science and Catalysis
ISSN: 0167-2991

Вых. Данные

Год: 2010, Страницы: 707-710 Страниц : 4 DOI: 10.1016/s0167-2991(10)75141-7

Авторы

Isaeva Vera I. ¹ , Tkachenko Olga P. ¹ , Mishin Igor V. ¹ , Afonina Elena V. ¹ , Kapustin Gennady I. ¹ , Kozlova Ludmila.M. ¹ , Grünert Wolfgang ² , Kustov Leonid M. ¹

Организации

1	N.D. Zelinsky Institute of Organic Chemistry RAS
2	Ruhr University Bochum

The novel Zn-derived heteroaromatic metal organic frameworks (MOFs) based on 2(5)- pyridinedicarboxylate and 2(5)-pyrazinedicarboxylate ligands were synthesized. In order to elucidate the framework nature effect, a reference sample of aromatic MOF-5 derived from Zn4O clusters and benzene-1,4-dicarboxylate linkers was prepared. The variation of the preparation procedure parameters in respect to the MOF texture (porosity, surface area) was accomplished. The synthesized metal organic frameworks were characterized by the combination of the physicochemical methods: XRD, volumetric N2 adsorption/desorption, DRIFT, and XAS. The catalytic activity of the Pd-containing MOFs in the liquid-phase hydrogenation of cyclohexene (20 °C, PH2 1atm) was higher than that of Pd on activated carbon.

Isaeva V.I. , Tkachenko O.P. , Mishin I.V. , Afonina E.V. , Kapustin G.I. , Kozlova L.M. , Grünert W. , Kustov L.M.
Novel dicarboxylate heteroaromatic metal organic frameworks as the catalyst supports for the hydrogenation reaction
Studies in Surface Science and Catalysis. 2010. P.707-710. DOI: 10.1016/s0167-2991(10)75141-7 Scopus OpenAlex

Scopus:	2-s2.0-78649378404
OpenAlex:	W1513114285