Unusual binuclear alkoxomolybdenum(V) complex free of oxo groups: synthesis, structure and IR spectra

Unusual binuclear alkoxomolybdenum(V) complex free of oxo groups: synthesis, structure and IR spectra Научная публикация

Журнал

Mendeleev Communications
ISSN: 0959-9436

Вых. Данные

Год: 2006, Том: 16, Номер: 6, Страницы: 307-308 Страниц : 2 DOI: 10.1070/mc2006v016n06abeh002426

Авторы

Bardina Nadezhda V. ¹ , Bazhenova Tamara A. ¹ , Lyssenko Konstantin A. ² , Antipin Mikhail Yu. ² , Shulga Yurii M. ¹ , Filina Tatyana A. ¹ , Shestakov Alexander F. ¹

Организации

1	Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
2	A. N. Nesmeyanov Institute of Organoelement Compounds RAS

The interaction of MoCl5 with NaOMe in methanol led to the formation of a new neutral binuclear molybdenum(V) alkoxo complex with Cl ligands, trans-[Cl(OMe)3Mo(μ-OMe)2Mo(OMe)3Cl]; the complex was characterised by X-ray analysis, IR spectroscopy and DFT quantum-chemical calculations.

Bardina N.V. , Bazhenova T.A. , Lyssenko K.A. , Antipin M.Y. , Shulga Y.M. , Filina T.A. , Shestakov A.F.
Unusual binuclear alkoxomolybdenum(V) complex free of oxo groups: synthesis, structure and IR spectra
Mendeleev Communications. 2006. V.16. N6. P.307-308. DOI: 10.1070/mc2006v016n06abeh002426 WOS OpenAlex

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