Obtention d'un complexe de fer(II) ne comportant que des ligands σ, le bis-lithium tetranaphtylferrate, et sa transformation par action de C3H7Li en un complexe reducteur de N2 Научная публикация
| Журнал |
Journal of Organometallic Chemistry
ISSN: 0022-328X |
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| Вых. Данные | Год: 1981, Том: 222, Номер: 1, Страницы: C1-C4 Страниц : DOI: 10.1016/s0022-328x(00)89026-9 | ||||
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Реферат:
FeCl3 and naphthyllithium in ether at −30°C afford an iron(II) complex containing σ-ligands only, dilithium tetranaphthyl ferrate, which is stable at room temperature, in the absence of air and water and crystallises with two moles of ether. The anion of this “ate” complex is tetrahedral (X-ray crystal Structure). This is the first example of an iron(II) compound containing σ-Arligands only. The complex does not react with N2, but with C3H7Li or C6H5Li it forms a compound which reduces N2.
Библиографическая ссылка:
Bagenova T.A.
, Shilova A.K.
, Deschamps E.
, Gruselle M.
, Leny G.
, Tchoubar B.
Obtention d'un complexe de fer(II) ne comportant que des ligands σ, le bis-lithium tetranaphtylferrate, et sa transformation par action de C3H7Li en un complexe reducteur de N2
Journal of Organometallic Chemistry. 1981. V.222. N1. P.C1-C4. DOI: 10.1016/s0022-328x(00)89026-9 WOS Scopus OpenAlex
Obtention d'un complexe de fer(II) ne comportant que des ligands σ, le bis-lithium tetranaphtylferrate, et sa transformation par action de C3H7Li en un complexe reducteur de N2
Journal of Organometallic Chemistry. 1981. V.222. N1. P.C1-C4. DOI: 10.1016/s0022-328x(00)89026-9 WOS Scopus OpenAlex
Идентификаторы БД:
| Web of science: | WOS:A1981MU45700015 |
| Scopus: | 2-s2.0-8344263516 |
| OpenAlex: | W2043894359 |