Structure of the intermediate iron(0) complex isolated from the dinitrogen fixing system LiPh + FeCl3

Structure of the intermediate iron(0) complex isolated from the dinitrogen fixing system LiPh + FeCl3 Научная публикация

Журнал

Journal of Organometallic Chemistry
ISSN: 0022-328X

Вых. Данные

Год: 1983, Том: 244, Номер: 3, Страницы: 265-272 Страниц : 8 DOI: 10.1016/s0022-328x(00)98618-2

Авторы

Bazhenova T.A. ¹ , Lobkovskaya R.M. ¹ , Shibaeva R.P. ¹ , Shilov A.E. ¹ , Shilova A.K. ¹ , Gruselle M. ² , Leny G. ² , Tchoubar B. ²

Организации

1	Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
2	National Research Centre of Thiais

The structure of the complex Fe0(LiPh)4(Et2O)4, active towards dinitrogen, reveals a flat rectangular structure formed by carbon atoms of four phenyl rings linked by σ-bonds with Fe0 atom. The comparatively short interatomic distance between two carbon atoms of phenyl rings indicates some interaction between them. The possible mechanism of the reaction with N2 is considered.

Bazhenova T.A. , Lobkovskaya R.M. , Shibaeva R.P. , Shilov A.E. , Shilova A.K. , Gruselle M. , Leny G. , Tchoubar B.
Structure of the intermediate iron(0) complex isolated from the dinitrogen fixing system LiPh + FeCl3
Journal of Organometallic Chemistry. 1983. V.244. N3. P.265-272. DOI: 10.1016/s0022-328x(00)98618-2 WOS Scopus OpenAlex

Web of science:	WOS:A1983QH02800007
Scopus:	2-s2.0-0010423238
OpenAlex:	W1966362542

БД	Цитирований
OpenAlex	40
Scopus	35