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An effect of application of chiral aluminium alkoxides and amides as adducts to zirconium catalyzed carbo- and cycloalumination of olefins Научная публикация

Журнал Journal of Organometallic Chemistry
ISSN: 0022-328X
Вых. Данные Год: 2003, Том: 689, Номер: 2, Страницы: 444-453 Страниц : 10 DOI: 10.1016/j.jorganchem.2003.09.055
Авторы Khalilov Leonard M 1 , Parfenova Ludmila V 1 , Pechatkina Svetlana V 1 , Ibragimov Askhat G 1 , Genet Jean P 2 , Dzhemilev Usein M 1 , Beletskaya Irina P 3
Организации
1 Institute of Petrochemistry and Catalysis, Russian Academy of Sciences
2 Ecole Nationale Supérieure de Chimie de Paris
3 Lomonosov Moscow State University
Реферат: This paper is dedicated to a study of properties of the following novel optically active organoaluminium compounds (OACs): (1S,2S)-l,7,7-trimethyl-2-[(dialkylalumina)oxy]-bicyclo[2.2.1]heptanes and (1S)-N-(dialkylalumina)-6,7-dimethoxy-1-methyl-1,2,3,4- tetrahydroisoquinolines. The synthesis of the chiral OACs was carried out in the reaction of either natural camphor or salsolidine with both AlEt3 and i-Bu2AlH. The main goal of the research was to investigate the stereodifferentiating activity of the chiral OACs in the olefin carbo- and cycloalumination reactions, catalyzed by Cp2ZrCl2. The synthesis of the chiral OACs was carried out in the reaction of either natural camphor or salsolidine with both AlEt3 and i-Bu2AlH. The main goal of the research was to investigate the stereodifferentiating activity of the chiral OACs in the olefin carbo- and cycloalumination reactions, catalyzed by Cp2ZrCl2.
Библиографическая ссылка: Khalilov L.M. , Parfenova L.V. , Pechatkina S.V. , Ibragimov A.G. , Genet J.P. , Dzhemilev U.M. , Beletskaya I.P.
An effect of application of chiral aluminium alkoxides and amides as adducts to zirconium catalyzed carbo- and cycloalumination of olefins
Journal of Organometallic Chemistry. 2003. V.689. N2. P.444-453. DOI: 10.1016/j.jorganchem.2003.09.055 WOS Scopus OpenAlex
Идентификаторы БД:
Web of science: WOS:000188598000023
Scopus: 2-s2.0-0347653173
OpenAlex: W2064898162
Цитирование в БД:
БД Цитирований
OpenAlex 9
Scopus 10
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