On study of chemoselectivity of reaction of trialkylalanes with alkenes, catalyzed with Zr π-complexes Научная публикация
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Journal of Organometallic Chemistry
ISSN: 0022-328X |
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| Вых. Данные | Год: 2009, Том: 694, Номер: 23, Страницы: 3725-3731 Страниц : 7 DOI: 10.1016/j.jorganchem.2009.07.037 | ||
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Реферат:
The influence of the organoaluminium compound nature, Zr π-ligand environment, solvent type and reagent ratio on the chemoselectivity of reactions of trialkylalanes (AlMe3, AlEt3) with alkenes, catalyzed with L2ZrCl2 [L = Cp, Cp′ (Cp′-η5-C5H4CH3), Cp∗ (Cp∗-η5-C5(CH3)5), Ind (indenyl), Flu (fluorenyl)] has been studied. It is shown that in the case of AlMe3, the hydro- and carboalumination products, and alkene dimers are formed. The catalytic reaction of AlEt3 with the olefins yields aluminacyclopentanes altogether with the hydro- and carboalumination products, and the dimers. A probable reaction mechanism has been proposed.
Библиографическая ссылка:
Parfenova L.V.
, Gabdrakhmanov V.Z.
, Khalilov L.M.
, Dzhemilev U.M.
On study of chemoselectivity of reaction of trialkylalanes with alkenes, catalyzed with Zr π-complexes
Journal of Organometallic Chemistry. 2009. V.694. N23. P.3725-3731. DOI: 10.1016/j.jorganchem.2009.07.037 WOS Scopus РИНЦ OpenAlex
On study of chemoselectivity of reaction of trialkylalanes with alkenes, catalyzed with Zr π-complexes
Journal of Organometallic Chemistry. 2009. V.694. N23. P.3725-3731. DOI: 10.1016/j.jorganchem.2009.07.037 WOS Scopus РИНЦ OpenAlex
Идентификаторы БД:
| Web of science: | WOS:000270369400007 |
| Scopus: | 2-s2.0-70349425750 |
| РИНЦ: | 15311076 |
| OpenAlex: | W2170164599 |