Catalytic properties of cluster Grignard reagents Научная публикация
| Конференция |
10th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis 02-06 июл. 2001 , Lyon |
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| Журнал |
Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169 |
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| Вых. Данные | Год: 2002, Том: 182-183, Страницы: 395-398 Страниц : 4 DOI: 10.1016/s1381-1169(01)00513-1 | ||
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| Организации |
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Реферат:
Cluster Grignard reagents C6H5Mg4F have been obtained by direct magnesium cluster insertion into C–F bond in fluorobenzene with magnesium vapors co-condensates at low temperature. The appearance of metal cluster in organomagnesium molecule leads to unusual non-transition metal cluster compounds catalytic properties studied on halogen exchange reaction RF+R′Cl→RCl+R′F as example. Cluster Grignard reagents catalyze the fluorobenzene reaction with alkyl chlorides due to reversible magnesium cluster insertion into C–F and C–Cl bonds.
Библиографическая ссылка:
Tjurina L.A.
, Smirnov V.V.
, Beletskaya I.P.
Catalytic properties of cluster Grignard reagents
Journal of Molecular Catalysis A: Chemical. 2002. V.182-183. P.395-398. DOI: 10.1016/s1381-1169(01)00513-1 WOS Scopus РИНЦ OpenAlex
Catalytic properties of cluster Grignard reagents
Journal of Molecular Catalysis A: Chemical. 2002. V.182-183. P.395-398. DOI: 10.1016/s1381-1169(01)00513-1 WOS Scopus РИНЦ OpenAlex
Идентификаторы БД:
| Web of science: | WOS:000176269200040 |
| Scopus: | 2-s2.0-0037205114 |
| РИНЦ: | 13399521 |
| OpenAlex: | W2032808178 |