Synthesis of Cluster Alkyl and Aryl Grignard Reagents in Solution | Sciact

Synthesis of Cluster Alkyl and Aryl Grignard Reagents in Solution Научная публикация

Журнал

Organometallics
ISSN: 0276-7333 , E-ISSN: 1520-6041

Вых. Данные

Год: 2004, Том: 23, Номер: 6, Страницы: 1349-1351 Страниц : 3 DOI: 10.1021/om030633x

Авторы

Tjurina Ljudmila A. , Smirnov Vladimir V. , Potapov Denis A. , Nikolaev Sergei A. , Esipov Stanislav E. , Beletskaya Irina P.

Организации

1	Lomonosov Moscow State University
2	Shemyakin–Ovchinnikov Institute of Bioorganic Chemistry RAS

Cluster alkyl Grignard reagents, alkyltetramagnesium chlorides, have been obtained by exchange reaction between phenyltetramagnesium fluoride and organic halides in excess halide solution at room temperature. Transmetalation between PhCl, PhBr, and phenyltetramagnesium fluoride with the formation of PhMg4X (X = Cl, Br) has been shown to occur.

Tjurina L.A. , Smirnov V.V. , Potapov D.A. , Nikolaev S.A. , Esipov S.E. , Beletskaya I.P.
Synthesis of Cluster Alkyl and Aryl Grignard Reagents in Solution
Organometallics. 2004. V.23. N6. P.1349-1351. DOI: 10.1021/om030633x WOS Scopus РИНЦ OpenAlex

Web of science:	WOS:000220093200027
Scopus:	2-s2.0-1842481971
РИНЦ:	13448872
OpenAlex:	W2009934718

БД	Цитирований
OpenAlex	30
Scopus	29