Benzene alkylation with propylene over Ga, B and Al pentasils | Sciact

Benzene alkylation with propylene over Ga, B and Al pentasils Научная публикация

Конференция

Zeolites and Related Microporous Materials: State of the Art 1994 : 10th International Zeolite Conference
17-22 июл. 1994 , Garmisch-Partenkirchen

Журнал

Studies in Surface Science and Catalysis
ISSN: 0167-2991

Вых. Данные

Год: 1994, Том: 84, Страницы: 1797-1804 Страниц : 8 DOI: 10.1016/s0167-2991(08)63734-9

Авторы

Smirnov A.V. ¹ , Romanovsky B.V. ¹ , Ivanova I.I. ² , Derouane E.G. ² , Gabelica Z. ²

Организации

1	Lomonosov Moscow State University
2	University of Namur (FUNDP)

Benzene alkylation with propylene using Ga-, B- and Al-containing pentasil zeolites as catalysts was studied. Ga-zeolites were found to be more selective towards cumene formation than Al-zeolites, the overall activities being similar. The activity of Ga-containing catalysts increases with gallium content for zeolites having the concentration up to 0.5 atom of Ga per unit cell; at higher Ga-concentration it remained almost constant. Framework boron appeared to have no effect on the activity of MFI-catalysts.

Smirnov A.V. , Romanovsky B.V. , Ivanova I.I. , Derouane E.G. , Gabelica Z.
Benzene alkylation with propylene over Ga, B and Al pentasils
Studies in Surface Science and Catalysis. 1994. V.84. P.1797-1804. DOI: 10.1016/s0167-2991(08)63734-9

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