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Pt–Ga Catalysts Based on Highly Porous MCM-41 Silica for Propane Dehydrogenation Научная публикация

Журнал Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Вых. Данные Год: 2025, Том: 66, Номер: 1, Страницы: 65-75 Страниц : 11 DOI: 10.1134/s0023158425600129
Авторы Zubkov A.V. , Bugrova T.A. , Evdokimova E.V. , Mamontov G.V.
Организации
1 Tomsk State University, Tomsk, Russia
Реферат: Highly porous SiO2 supports with the MCM-41 structure were synthesized by a template method. The Pt–Ga catalysts for propane dehydrogenation were prepared using an impregnation method. The structure of the synthesized samples was studied by low-temperature nitrogen adsorption and X-ray diffraction (XRD) analysis, and the characteristics of catalyst reduction were studied by temperature-programmed reduction in hydrogen (TPR-H2). The catalytic properties were tested in the reaction of propane dehydrogenation, and the influence of a hydrogen additive to the reaction mixture on the activity of the catalysts was examined. The developed approach demonstrated the possibility of obtaining MCM-41-based materials characterized by an ordered mesoporous structure (mesopores of 3–4 nm in size) and a high specific surface area, which makes them promising for use as catalyst supports. It was found that the introduction of hydrogen into the reaction mixture led to an increase in the stability and activity of platinum catalysts.
Библиографическая ссылка: Zubkov A.V. , Bugrova T.A. , Evdokimova E.V. , Mamontov G.V.
Pt–Ga Catalysts Based on Highly Porous MCM-41 Silica for Propane Dehydrogenation
Kinetics and Catalysis. 2025. V.66. N1. P.65-75. DOI: 10.1134/s0023158425600129 WOS Scopus РИНЦ OpenAlex
Даты:
Поступила в редакцию: 22 мар. 2024 г.
Принята к публикации: 6 дек. 2024 г.
Опубликована online: 5 июн. 2025 г.
Идентификаторы БД:
Web of science: WOS:001502103900005
Scopus: 2-s2.0-105007143456
РИНЦ: 82395811
OpenAlex: W4410983365
Альметрики: