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Dual-Function Catalysts For Ring Opening of Cyclic Compounds Научная публикация

Конференция Spillover and mobility of species on solid surfaces : 5th International Conference on Spillover
08-08 авг. 2001 , el Escorial (Madrid)
Журнал Studies in Surface Science and Catalysis
ISSN: 0167-2991
Вых. Данные Год: 2001, Том: 138, Страницы: 307-314 Страниц : 8 DOI: 10.1016/s0167-2991(01)80043-4
Авторы Kustov L.M. 1 , Stakheev A.Yu. 1 , Vasina T.V. 1 , Masloboishchikova O.V. 1 , Khelkovskaya-Sergeeva E.G. 1 , Zeuthen P. 2
Организации
1 N.D. Zelinsky Institute of Organic Chemistry RAS
2 Haldor Topsoe A/S
Реферат: A series of Ni-containing catalysts were studied in the conversion of cyclohexane and decaline + n-octane mixture. Comparison of the performance of the catalyst bearing mainly metal active sites with acidic HY zeolite and the catalysts containing both functions revealed the importance of the acidic component for achieving high catalyst efficiency. Dual-function systems containing a metal function and strong acidity exhibited the best performance. It is shown that the strong acidity is particularly important for the ring opening of heavier naphthenes (decaline). Separation of these functions by using mixtures of an acid catalyst with a metal-containing system revealed the effect of spillover of reactive species in the course of the hydrocarbon conversion.
Библиографическая ссылка: Kustov L.M. , Stakheev A.Y. , Vasina T.V. , Masloboishchikova O.V. , Khelkovskaya-Sergeeva E.G. , Zeuthen P.
Dual-Function Catalysts For Ring Opening of Cyclic Compounds
Studies in Surface Science and Catalysis. 2001. V.138. P.307-314. DOI: 10.1016/s0167-2991(01)80043-4 Scopus OpenAlex
Идентификаторы БД:
Scopus: 2-s2.0-0035787242
OpenAlex: W2287047839
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OpenAlex 15
Scopus 13
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