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Study of Thermocatalytic Decomposition of Polyethylene and Polyvinyl Alcohol in the Presence of an Unsteady-State Fe-Containing Catalyst Научная публикация

Конференция 3 International conference on unsteady-state processes in catalysis
30 июн. - 3 июл. 1998 , St. Petersburg
Журнал Chemical Engineering Science
ISSN: 0009-2509
Вых. Данные Год: 1999, Том: 54, Номер: 20, Страницы: 4351-4357 Страниц : 7 DOI: 10.1016/S0009-2509(99)00160-8
Авторы Maksimova Nadezhda I. 1 , Krivoruchko Oleg P. 1
Организации
1 Boreskov Institute of Catalysis, pr. Akademika Lavrentieva, 5, 630090, Novosibirsk, Russia
Реферат: The thermal decomposition of low-density polyethylene (LDPE) and polyvinyl alcohol (PVA) in a nitrogen flow at a temperature range of 573–873 K was investigated in the presence of Fe-containing catalysts. In this temperature range decomposition of these polymers with formation of gaseous (C1–C4), liquid (C5–C30), and solid (carbon, carbide, graphite) products is observed. During this process, α-FeO(OH) used as a precursor of the catalyst is reduced to iron oxides and metal, and, therefore, it is in unsteady state. The unsteady state of catalyst allows one to affect on all stages of polymer decomposition. Gas chromatography-mass spectroscopy (GCMS) and X-ray diffractometry (XRD) show that the presence of the Fe-containing catalyst greatly affect both liquid and solid products of thermal decomposition of LDPE and PVA.
Библиографическая ссылка: Maksimova N.I. , Krivoruchko O.P.
Study of Thermocatalytic Decomposition of Polyethylene and Polyvinyl Alcohol in the Presence of an Unsteady-State Fe-Containing Catalyst
Chemical Engineering Science. 1999. V.54. N20. P.4351-4357. DOI: 10.1016/S0009-2509(99)00160-8 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact
Даты:
Опубликована online: 15 июл. 1999 г.
Опубликована в печати: 1 окт. 1999 г.
Идентификаторы БД:
Web of science: WOS:000081864700008
Scopus: 2-s2.0-0032728807
РИНЦ: 13309987
Chemical Abstracts: 1999:511965
Chemical Abstracts (print): 131:272784
OpenAlex: W2063858002
Sciact: 9468
Цитирование в БД:
БД Цитирований
Scopus 22
OpenAlex 20
Альметрики: