Palladium carboxylate/boron trifluoride etherate catalyst system for the selective dimerization of styrene Научная публикация
| Журнал |
Catalysis Communications
ISSN: 1566-7367 |
||||
|---|---|---|---|---|---|
| Вых. Данные | Год: 2006, Том: 8, Номер: 4, Страницы: 677-680 Страниц : 4 DOI: 10.1016/j.catcom.2006.08.029 | ||||
| Авторы |
|
||||
| Организации |
|
Реферат:
The selective dimerization of styrene to 1,3-diphenyl-1-butene with Pd(carboxylate)2 + BF3OEt2 catalyst system in both “phosphine-free” and “phosphine-modified” fashions has been investigated. For the Pd(OAc)2 + 2PR3 + 7BF3OEt2 catalyst system, a TON of 145 000 and 90% selectivity to dimers have been achieved at 80 °C for 5 h. This TON is twice as large as compared to that achieved with the Pd(β-diketonate)2-based systems. Styrene dimers up to 95% consist of trans-1,3-diphenyl-1-butene. The simplicity of this catalyst system composition might be of industrial importance.
Библиографическая ссылка:
Tkach V.S.
, Myagmarsuren G.
, Suslov D.S.
, Mesyef M.
, Shmidt F.K.
Palladium carboxylate/boron trifluoride etherate catalyst system for the selective dimerization of styrene
Catalysis Communications. 2006. V.8. N4. P.677-680. DOI: 10.1016/j.catcom.2006.08.029 WOS Scopus OpenAlex
Palladium carboxylate/boron trifluoride etherate catalyst system for the selective dimerization of styrene
Catalysis Communications. 2006. V.8. N4. P.677-680. DOI: 10.1016/j.catcom.2006.08.029 WOS Scopus OpenAlex
Идентификаторы БД:
| Web of science: | WOS:000245793300008 |
| Scopus: | 2-s2.0-33847420831 |
| OpenAlex: | W2027871394 |