An easy way to Pd–Zn nanoalloy with defined composition from a heterobimetallic Pd(μ–OOCMe)4Zn(OH2) complex as evidenced by XAFS and XRD

An easy way to Pd–Zn nanoalloy with defined composition from a heterobimetallic Pd(μ–OOCMe)4Zn(OH2) complex as evidenced by XAFS and XRD Научная публикация

Журнал

Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X

Вых. Данные

Год: 2006, Том: 112, Номер: 3-4, Страницы: 155-161 Страниц : 7 DOI: 10.1007/s10562-006-0196-6

Авторы

Tkachenko Olga P. ¹ , Stakheev Alexander Yu. ¹ , Kustov Leonid M. ¹ , Mashkovsky Igor V. ¹ , van den Berg Maurits ² , Grünert Wolfgang ² , Kozitsyna Natalya Yu. ³ , Dobrokhotova Zhanna V. ³ , Zhilov Valery I. ³ , Nefedov Sergei E. ³ , Vargaftik Michael N. ³ , Moiseev Ilya I. ³

Организации

1	N. D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, Moscow, Russian Federation
2	Laboratory of Industrial Chemistry, Ruhr University Bochum, Bochum, Germany.
3	N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, RUSSIAN FEDERATION

The heterobimetallic lantern complex Pd(μ-OOCMe)4Zn(OH2) was found to be readily reduced with H2 under fairly mild conditions (150–250 °C, 5–10% H2/He) both in the carbon-supported and crystalline states to afford a Pd–Zn nanoalloy as evidenced by the ICP elemental analysis, EXAFS, XANES and XRD data.

Tkachenko O.P. , Stakheev A.Y. , Kustov L.M. , Mashkovsky I.V. , van den Berg M. , Grünert W. , Kozitsyna N.Y. , Dobrokhotova Z.V. , Zhilov V.I. , Nefedov S.E. , Vargaftik M.N. , Moiseev I.I.
An easy way to Pd–Zn nanoalloy with defined composition from a heterobimetallic Pd(μ–OOCMe)4Zn(OH2) complex as evidenced by XAFS and XRD
Catalysis Letters. 2006. V.112. N3-4. P.155-161. DOI: 10.1007/s10562-006-0196-6 WOS Scopus OpenAlex

Web of science:	WOS:000242708100005
Scopus:	2-s2.0-33845486285
OpenAlex:	W2077740555

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