Hydroalkylation of benzene and ethylbenzene over Ru- and Ni-containing zeolite catalysts – novel catalytic route for ethylcyclohexylbenzene synthesis Научная публикация
| Конференция |
15th International Zeolite Conference 12-17 авг. 2007 , Beijing |
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| Журнал |
Studies in Surface Science and Catalysis
ISSN: 0167-2991 |
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| Вых. Данные | Год: 2007, Том: 170, Страницы: 1228-1235 Страниц : 8 DOI: 10.1016/s0167-2991(07)80982-7 | ||||||
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Реферат:
The reaction of benzene and ethylbenzene has been studied over zeolite catalysts with different structural type (BEA, MFI), Si/Al ratio (10 – 200 for BEA) and Ru and Ni contents (0.5 – 1%) in the temperature range of 150 – 230 0C, under 0.2 – 1 MPa and WHSV of 1 – 64 g/g*h. The main reaction pathways were found to include benzene and ethylbenzene hydrogenation towards cyclohexane and ethylcyclohexane, hydroalkylation into cyclohexylbenzene, ethylcyclohexylbenzene and diethylcyclohexylbenzene and formation of ethylbiphenyls or diethylbiphenyls followed by hydrogenation. The major reaction products were para- and meta-ethylcyclohexylbenzenes. The results have demonstrated that hydroalkylation of benzene and ethylbenzene over metal containing zeolites is a perspective route for synthesis of ethylcyclohexylbenzene, which can find application in production of phenylstyrene.
Библиографическая ссылка:
Ivanova I.I.
, Borodina I.B.
, Ponomareva O.A.
, Yuschenko V.V.
, Fajula F.
, Bousquet J.
Hydroalkylation of benzene and ethylbenzene over Ru- and Ni-containing zeolite catalysts – novel catalytic route for ethylcyclohexylbenzene synthesis
Studies in Surface Science and Catalysis. 2007. V.170. P.1228-1235. DOI: 10.1016/s0167-2991(07)80982-7 Scopus OpenAlex
Hydroalkylation of benzene and ethylbenzene over Ru- and Ni-containing zeolite catalysts – novel catalytic route for ethylcyclohexylbenzene synthesis
Studies in Surface Science and Catalysis. 2007. V.170. P.1228-1235. DOI: 10.1016/s0167-2991(07)80982-7 Scopus OpenAlex
Идентификаторы БД:
| Scopus: | 2-s2.0-35348908337 |
| OpenAlex: | W1607449386 |