The Effect of Heat-Treatment Temperature of Cobalt–Boron Catalysts on Their Activity in Sodium Borohydride Hydrolysis Научная публикация
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EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” 30 авг. - 4 сент. 2015 , Казань |
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| Журнал |
Topics in Catalysis
ISSN: 1022-5528 , E-ISSN: 1572-9028 |
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| Вых. Данные | Год: 2016, Том: 59, Номер: 15, Страницы: 1431-1437 Страниц : 7 DOI: 10.1007/s11244-016-0664-1 | ||||
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Реферат:
The activity of cobalt–boron catalysts in sodium borohydride hydrolysis has been correlated with change of
structure in the active component of the catalysts upon their thermal treatment. It was shown that at temperatures to 300 C there takes place loss of water and hydrogen from the catalysts without noticeable changes in activity. At temperatures above 300 C the amorphous cobalt boride particles undergo crystallization to produce metallic cobalt with a hexagonal structure and this is seemingly the cause of the substantial fall in the rate of hydrogen generation in the presence of cobalt–boron catalysts.
Библиографическая ссылка:
Netskina O.V.
, Ozerova A.M.
, Komova O.V.
, Kochubey D.I.
, Kanazhevskiy V.V.
, Ishchenko A.V.
, Simagina V.I.
The Effect of Heat-Treatment Temperature of Cobalt–Boron Catalysts on Their Activity in Sodium Borohydride Hydrolysis
Topics in Catalysis. 2016. V.59. N15. P.1431-1437. DOI: 10.1007/s11244-016-0664-1 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact
The Effect of Heat-Treatment Temperature of Cobalt–Boron Catalysts on Their Activity in Sodium Borohydride Hydrolysis
Topics in Catalysis. 2016. V.59. N15. P.1431-1437. DOI: 10.1007/s11244-016-0664-1 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact
Даты:
| Опубликована online: | 20 июл. 2016 г. |
| Опубликована в печати: | 1 сент. 2016 г. |
Идентификаторы БД:
| Web of science: | WOS:000382849100017 |
| Scopus: | 2-s2.0-84984923152 |
| РИНЦ: | 27024444 |
| Chemical Abstracts: | 2016:1215765 |
| Chemical Abstracts (print): | 165:369024 |
| OpenAlex: | W2491682029 |
| Sciact: | 19850 |