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Joint Transformations of H-Dodecane and 2-Methylthiophene on Bizeolite Cracking Catalysts Containing Phosphorus-modified Zeolite ZSM-5 Научная публикация

Конференция VI Всероссийская научно молодежная школа-конференция "Химия под знаком СИГМА: исследования, инновации, технологии"
18-20 мая 2020 , Омск
Журнал AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616
Вых. Данные Год: 2020, Том: 2301, Номер статьи : 040008, Страниц : 8 DOI: 10.1063/5.0032913
Авторы Plekhova K.S. 1 , Yurtaeva A.S. 1 , Gulyaeva T.I. 1 , Potapenko O.V. 1 , Sorokina T.P. 1 , Doronin V.P. 1
Организации
1 Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis, 54, Neftezavodskaya Str., Omsk, 644040, Russian Federation
Реферат: The effect of the phosphorus in zeolite ZSM-5 as a component of cracking catalysts, was studied on the conversion of pure n-dodecane, as well as its mixture with 2-methylthiophene in an amount of 5000 ppm sulfur. It was established that the modification of zeolite ZSM-5 with phosphorus affects the catalytic activity of catalysts based on it. The maximum yield of C2-C4-olefinic hydrocarbons is observed at a phosphorus content of 4 wt. % in zeolite ZSM-5. Modification of zeolite ZSM-5 with phosphorus reduces the degree of conversion of thiophene compounds by reducing the contribution of intermolecular hydrogen transfer and as a result increasing the content of sulfur compounds in cracking liquid products.
Библиографическая ссылка: Plekhova K.S. , Yurtaeva A.S. , Gulyaeva T.I. , Potapenko O.V. , Sorokina T.P. , Doronin V.P.
Joint Transformations of H-Dodecane and 2-Methylthiophene on Bizeolite Cracking Catalysts Containing Phosphorus-modified Zeolite ZSM-5
AIP Conference Proceedings. 2020. V.2301. 040008 :1-8. DOI: 10.1063/5.0032913 Scopus РИНЦ OpenAlex Sciact publication_identifier_short.sciact_ihcp_identifier_type
Идентификаторы БД:
Scopus: 2-s2.0-85098073342
РИНЦ: 45062871
OpenAlex: W3113175218
Sciact: 49889
publication_identifier.sciact_ihcp_identifier_type: 3320
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БД Цитирований
Scopus 1
OpenAlex 2
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