Hydrolytic hydrogenation of cellulose in subcritical water with the use of the Ru-containing polymeric catalysts

Hydrolytic hydrogenation of cellulose in subcritical water with the use of the Ru-containing polymeric catalysts Научная публикация

Конференция

4th European Conference on Environmental Applications of Advanced Oxidation Processes
21-24 окт. 2015 , Athens

Журнал

Catalysis Today
ISSN: 0920-5861

Вых. Данные

Год: 2016, Том: 280, Страницы: 45-50 Страниц : 6 DOI: 10.1016/j.cattod.2016.09.001

Авторы

Matveeva Valentina G. , Sulman Esther M. , Manaenkov Oleg V. , Filatova Anastasia E. , Kislitza Olga V. , Sidorov Alexander I. , Doluda Valentin Yu. , Sulman Mikhail G. , Rebrov Evgeny V.

Организации

1	Tver State Technical University

The study presents the results of cellulose hydrolytic hydrogenation process in subcritical water in the presence of Ru-containing catalysts based on hypercrosslinked polystyrene (HPS) MN-270 and its functionalized analogues: NH2-HPS (MN-100) and SO3H-HPS (MN-500). It was shown that the replacement of the traditional support (carbon) by HPS increases the yield of the main cellulose conversion products – polyols – important intermediates for the chemical industry. The catalysts were characterized using transmission electron microscopy (TEM), high resolution TEM, and porosity measurements. Catalytic studies demonstrated that the catalyst containing 1.0% Ru and based on MN-270 is the most active. The total yield of sorbitol and mannitol was 50% on the average at 85% cellulose conversion.

Matveeva V.G. , Sulman E.M. , Manaenkov O.V. , Filatova A.E. , Kislitza O.V. , Sidorov A.I. , Doluda V.Y. , Sulman M.G. , Rebrov E.V.
Hydrolytic hydrogenation of cellulose in subcritical water with the use of the Ru-containing polymeric catalysts
Catalysis Today. 2016. V.280. P.45-50. DOI: 10.1016/j.cattod.2016.09.001 WOS Scopus OpenAlex

Web of science:	WOS:000388154000008
Scopus:	2-s2.0-84994059790
OpenAlex:	W2520942833