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Cellulose Conversion Into Hexitols and Glycols in Water: Recent Advances in Catalyst Development Научная публикация

Журнал Frontiers in Chemistry
ISSN: 2296-2646
Вых. Данные Год: 2019, Том: 7, Номер статьи : 834, Страниц : 8 DOI: 10.3389/fchem.2019.00834
Авторы Manaenkov Oleg V. 1 , Kislitsa Olga V. 1 , Matveeva Valentina G. 1,2 , Sulman Ester M. 1,2 , Sulman Mikhail G. 3,1 , Bronstein Lyudmila M. 3,4,5
Организации
1 Department of Biotechnology, Chemistry, and Standardization, Tver State Technical University, Tver, Russia
2 Regional Technological Center, Tver State University, Tver, Russia
3 A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia
4 Department of Chemistry, Indiana University, Bloomington, IN, United States
5 Department of Physics, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia
Реферат: Conversion of biomass cellulose to value-added chemicals and fuels is one of the most important advances of green chemistry stimulated by needs of industry. Here we discuss modern trends in the development of catalysts for two processes of cellulose conversion: (i) hydrolytic hydrogenation with the formation of hexitols and (ii) hydrogenolysis, leading to glycols. The promising strategies include the use of subcritical water which facilitates hydrolysis, bifunctional catalysts which catalyze not only hydrogenation, but also hydrolysis, retro-aldol condensation, and isomerization, and pretreatment (milling) of cellulose together with catalysts to allow an intimate contact between the reaction components. An important development is the replacement of noble metals in the catalysts with earth-abundant metals, bringing down the catalyst costs, and improving the environmental impact.
Библиографическая ссылка: Manaenkov O.V. , Kislitsa O.V. , Matveeva V.G. , Sulman E.M. , Sulman M.G. , Bronstein L.M.
Cellulose Conversion Into Hexitols and Glycols in Water: Recent Advances in Catalyst Development
Frontiers in Chemistry. 2019. V.7. 834 :1-8. DOI: 10.3389/fchem.2019.00834 WOS Scopus OpenAlex
Идентификаторы БД:
Web of science: WOS:000502725200001
Scopus: 2-s2.0-85076902631
OpenAlex: W2991512651
Альметрики: