Catalytic Myrtenol Amination over Gold, Supported on Alumina Doped with Ceria and Zirconia

Catalytic Myrtenol Amination over Gold, Supported on Alumina Doped with Ceria and Zirconia Научная публикация

Журнал

Catalysis for Sustainable Energy
ISSN: 2084-6819

Вых. Данные

Год: 2018, Том: 5, Номер: 1, Страницы: 49-58 Страниц : 10 DOI: 10.1515/cse-2018-0007

Авторы

Demidova Yu.S. ^1,2 , Simakova I.L. ² , Suslov E.V. ³ , Volcho K.P. ^2,3 , Salakhutdinov N.F. ^2,3 , Simakov A. ⁴ , Murzin D.Yu. ⁵

Организации

1	Boreskov Institute of Catalysis, pr. Lavrentieva, 5, 630090, Novosibirsk, Russia
2	Novosibirsk State University, Pirogova 2, 630090, Novosibirsk, Russia
3	Novosibirsk Institute of Organic Chemistry, pr. Lavrentieva, 9, 630090, Novosibirsk, Russia
4	Universidad Nacional Autónoma de México, Centro de Nanociencias y Nanotecnología, km. 107 carretera Tijuana a Ensenada, C.P. 22860, Ensenada, Baja California, México
5	Johan Gadolin Process Chemistry Centre, Åbo Akademi University, Biskopsgatan 8, FI-20500, Turku/Åbo, Finland

In the current work gold catalysts supported on both commercial oxides and oxides synthesized by the sol-gel method were used for the one-pot alcohol amination of myrtenol. In general, utilization of metal oxides synthesized by the sol-gel method as the gold catalyst support enhanced the knowledge regarding key parameters determining catalytic behavior. Synthesized alumina was characterized by stronger acid sites favoring primary amine accumulation on the catalyst surface, as compared to the commercial oxide. Utilization of mixed metal oxides synthesized by the sol-gel method resulted in the non-additive behavior of different oxides enhancing the catalytic activity. Introduction of ceria into alumina modified the support basicity resulting in more efficient alcohol activation.

Demidova Y.S. , Simakova I.L. , Suslov E.V. , Volcho K.P. , Salakhutdinov N.F. , Simakov A. , Murzin D.Y.
Catalytic Myrtenol Amination over Gold, Supported on Alumina Doped with Ceria and Zirconia

Catalysis for Sustainable Energy. 2018. V.5. N1. P.49-58. DOI: 10.1515/cse-2018-0007 РИНЦ CAPlus OpenAlex Sciact

Полный текст от издателя

Поступила в редакцию:	29 окт. 2018 г.
Принята к публикации:	8 нояб. 2018 г.
Опубликована в печати:	1 дек. 2018 г.
Опубликована online:	31 дек. 2018 г.

РИНЦ:	44642882
Chemical Abstracts:	2019:2274459
OpenAlex:	W2917806931
Sciact:	31387

БД	Цитирований
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