The Origin of Self-Sustained Reaction-Rate Oscillations in the Oxidation of Methane over Nickel: An Operando XRD and Mass Spectrometry Study Научная публикация
| Журнал |
Catalysis Science & Technology
ISSN: 2044-4761 |
||||||
|---|---|---|---|---|---|---|---|
| Вых. Данные | Год: 2017, Том: 7, Страницы: 1646-1649 Страниц : 4 DOI: 10.1039/C6CY02673G | ||||||
| Авторы |
|
||||||
| Организации |
|
Реферат:
The self-sustained kinetic oscillations in the catalytic oxidation of methane over Ni foil have been studied at atmospheric pressure using an X-ray diffraction technique and mass spectrometry. It has been shown that the regular reaction-rate oscillations appear under oxygen-deficient conditions and the period of oscillations varies between approximately 200 and 4000 s. The operando measurements have revealed a higher activity of metallic Ni in the reaction than NiO oxide and have unambiguously showed that the oscillations arise due to the reversible bulk oxidation of Ni to NiO.
Библиографическая ссылка:
Saraev A.A.
, Vinokurov Z.S.
, Kaichev V.V.
, Shmakov A.N.
, Bukhtiyarov V.I.
The Origin of Self-Sustained Reaction-Rate Oscillations in the Oxidation of Methane over Nickel: An Operando XRD and Mass Spectrometry Study
Catalysis Science & Technology. 2017.
V.7. P.1646-1649. DOI: 10.1039/C6CY02673G
WOS
Scopus
РИНЦ
CAPlus
OpenAlex
Sciact
The Origin of Self-Sustained Reaction-Rate Oscillations in the Oxidation of Methane over Nickel: An Operando XRD and Mass Spectrometry Study
Catalysis Science & Technology. 2017.
V.7. P.1646-1649. DOI: 10.1039/C6CY02673G
WOS
Scopus
РИНЦ
CAPlus
OpenAlex
Sciact
Файлы:
Полный текст от издателя
Даты:
| Поступила в редакцию: | 24 дек. 2016 г. |
| Принята к публикации: | 23 мар. 2017 г. |
| Опубликована online: | 23 мар. 2017 г. |
| Опубликована в печати: | 21 апр. 2017 г. |
Идентификаторы БД:
| Web of science: | WOS:000399919200002 |
| Scopus: | 2-s2.0-85022098636 |
| РИНЦ: | 31052998 |
| Chemical Abstracts: | 2017:477882 |
| OpenAlex: | W2598464360 |
| Sciact: | 21618 |