The Conversion of Neopentane on Supported Catalysts Pt + W/SiO2 and Pt + Mo/SiO2 Obtained through Oganometallic compounds of Pt, W and Mo

The Conversion of Neopentane on Supported Catalysts Pt + W/SiO2 and Pt + Mo/SiO2 Obtained through Oganometallic compounds of Pt, W and Mo Научная публикация

Журнал

Journal of Molecular Catalysis
ISSN: 0304-5102

Вых. Данные

Год: 1978, Том: 4, Номер: 1, Страницы: 49-57 Страниц : 9 DOI: 10.1016/0304-5102(78)85034-2

Авторы

Kuznetsov Boris N. ¹ , Yermakov Yu.I. ¹ , Boudart Michel ² , Collman James P. ³

Организации

1	Institute of Catalysis, Siberian Branch of the U.S.S.R. Academy of Science, Novosibirsk (U.S.S.R.)
2	Department of Chemical Engineering, Stanford University, Stanford, Calif. 94305 (U.S.A.)
3	Department of Chemistry, Stanford University, Stanford, Calif. 94305 (U.S.A.)

The conversion of neopentane has been studied on Pt/SiO2, Pt + W/SiO2 and Pt + Mo/SiO2 catalysts. The bimetallic samples exhibit a decreased selectivity towards isomerization but increased activity toward hydrogenolysis when compared with the sample containing platinum only. Everything happens as if combining Pt with W or Mo had moved Pt toward the left in the Periodic Table, although it must be noted that W/SiO2 and Mo/SiO2 samples prepared in the same way as the bimetallic catalysts were totally devoid of any catalytic activity.

Kuznetsov B.N. , Yermakov Y.I. , Boudart M. , Collman J.P.
The Conversion of Neopentane on Supported Catalysts Pt + W/SiO2 and Pt + Mo/SiO2 Obtained through Oganometallic compounds of Pt, W and Mo
Journal of Molecular Catalysis. 1978. V.4. N1. P.49-57. DOI: 10.1016/0304-5102(78)85034-2 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact

Поступила в редакцию:	11 июл. 1977 г.
Опубликована в печати:	1 мая 1978 г.
Опубликована online:	2 окт. 2001 г.

Web of science:	WOS:A1978EX32200005
Scopus:	2-s2.0-0009017845
РИНЦ:	30810945
Chemical Abstracts:	1978:442283
Chemical Abstracts (print):	89:42283
OpenAlex:	W2078699506
Sciact:	16282

БД	Цитирований
Scopus	25
OpenAlex	24