Oxidation of Cycloalkenes and Methylenecycloalkanes by Palladium (II) Complexes: Part I. NMR Study on the Mechanism of the Formation of Ring-Contracted and Ring-Opened Products in the Oxidation of 1-Methylcyclobutene Научная публикация
| Журнал |
Journal of Molecular Catalysis
ISSN: 0304-5102 |
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| Вых. Данные | Год: 1993, Том: 83, Номер: 3, Страницы: 287-300 Страниц : 14 DOI: 10.1016/0304-5102(93)87039-B | ||
| Авторы |
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| Организации |
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Реферат:
Oxidation of 1-methylcyclobutene (1) by PdCl2L2 and PdCl(NO2)L2 (LCD3CN) in methylene chloride was studied with 1H and 13C NMR. Reaction of 1 with PdCl2L2 leads to the formation of the stable ring-opened 1-3-η3-π-allyl palladium complex (2). With the addition of an equimolar quantity of PdCl(NO2)L2 to the solution of complex 2, the allylic oxidation of 2 proceeds slowly via the intermediate formation of another 1-3-η3-π-allyl palladium complex (3). When reacting directly with PdCl(NO2)L2, 1 undergoes palladium (II)-catalyzed ring contraction to give cyclopropyl methyl ketone. Kinetic and spectral data indicate the formation of an organometallic intermediate, a product of the β-nitritopalladation of the parent olefin 1.
Библиографическая ссылка:
Beck I.E.
, Gusevskaya E.V.
, Golovin A.V.
, Likholobov V.A.
Oxidation of Cycloalkenes and Methylenecycloalkanes by Palladium (II) Complexes: Part I. NMR Study on the Mechanism of the Formation of Ring-Contracted and Ring-Opened Products in the Oxidation of 1-Methylcyclobutene
Journal of Molecular Catalysis. 1993. V.83. N3. P.287-300. DOI: 10.1016/0304-5102(93)87039-B WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact
Oxidation of Cycloalkenes and Methylenecycloalkanes by Palladium (II) Complexes: Part I. NMR Study on the Mechanism of the Formation of Ring-Contracted and Ring-Opened Products in the Oxidation of 1-Methylcyclobutene
Journal of Molecular Catalysis. 1993. V.83. N3. P.287-300. DOI: 10.1016/0304-5102(93)87039-B WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact
Даты:
| Поступила в редакцию: | 10 сент. 1992 г. |
| Принята к публикации: | 20 мар. 1993 г. |
| Опубликована в печати: | 30 июл. 1993 г. |
| Опубликована online: | 2 окт. 2001 г. |
Идентификаторы БД:
| Web of science: | WOS:A1993LQ32700003 |
| Scopus: | 2-s2.0-0027627787 |
| РИНЦ: | 31642027 |
| Chemical Abstracts: | 1994:54011 |
| Chemical Abstracts (print): | 120:54011 |
| OpenAlex: | W1533372520 |
| Sciact: | 12866 |