Oxidation of Water by Ru(bpy)33+ in the Presence of Co(III) and Fe(III) Colloidal Hydroxides as Catalysts Научная публикация
| Журнал |
Journal of Molecular Catalysis
ISSN: 0304-5102 |
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| Вых. Данные | Год: 1987, Том: 43, Номер: 2, Страницы: 171-181 Страниц : 11 DOI: 10.1016/0304-5102(87)87004-9 | ||
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Реферат:
The reaction kinetics of water oxidation by Ru(bpy)33+ in the presence of Co(III) and Fe(III) colloidal hydroxides are studied as a function of pH, catalyst concentration and simple and complex salt additives. It was found that the kinetics of O2 formation and that of oxidant consumption differ due to side oxidation reactions. A reaction mechanism taking into account the ion exchange properties of the catalyst surface hydroxo groups and suggesting dioxygen formation on two neighbouring catalytically active centres is proposed.
Библиографическая ссылка:
Elizarova G.L.
, Matvienko L.G.
, Parmon V.N.
Oxidation of Water by Ru(bpy)33+ in the Presence of Co(III) and Fe(III) Colloidal Hydroxides as Catalysts
Journal of Molecular Catalysis. 1987. V.43. N2. P.171-181. DOI: 10.1016/0304-5102(87)87004-9 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact
Oxidation of Water by Ru(bpy)33+ in the Presence of Co(III) and Fe(III) Colloidal Hydroxides as Catalysts
Journal of Molecular Catalysis. 1987. V.43. N2. P.171-181. DOI: 10.1016/0304-5102(87)87004-9 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact
Даты:
| Поступила в редакцию: | 13 мар. 1987 г. |
| Принята к публикации: | 21 июл. 1987 г. |
| Опубликована в печати: | 1 дек. 1987 г. |
| Опубликована online: | 2 окт. 2001 г. |
Идентификаторы БД:
| Web of science: | WOS:A1987L226200004 |
| Scopus: | 2-s2.0-0023602635 |
| РИНЦ: | 28450207 |
| Chemical Abstracts: | 1988:101763 |
| Chemical Abstracts (print): | 108:101763 |
| OpenAlex: | W1969861725 |
| Sciact: | 12828 |