Реферат: Sulphide (Ni,W)/SiO2 and (Ni,MO)/SiO2 catalysts prepared by decomposition of surface organometallic complexes in H2S have been studied by X-ray photoelectron spectroscopy. The binding energy of electrons in the Ni 2p3/2 level has been found to increase simultaneously with decrease of that on W 4f7/2 (Mo 3d5/2) level in bimetallic catalysts, compared with the corresponding values for monometallic sulphide catalysts. This effect is ascribed to the partial transfer of electron density from nickel atoms onto tungsten (molybdenum) atoms through the formation of mixed surface sulphides. A shift in the binding energies of Ni 2p3/2 and W 4f7/2 levels in supported catalysts in comparison with those in bulk sulphides is suggested to be evidence of chemical interaction between the supported sulphides and the silica surface.

Библиографическая ссылка: Shepelin A.P. , Zhdan P.A. , Burmistrov V.A. , Startsev A.N. , Yermakov Y.I.
Sulphide Catalysts on Silica as a Support. III. X-ray Photoelectron Spectroscopy Study
Applied Catalysis. 1984. V.11. N1. P.29-34. DOI: 10.1016/S0166-9834(00)84037-3 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact

Даты:

Поступила в редакцию:	5 июл. 1983 г.
Принята к публикации:	25 нояб. 1983 г.
Опубликована в печати:	1 янв. 1984 г.
Опубликована online:	2 окт. 2001 г.

Идентификаторы БД:

Web of science:	WOS:A1984TD12300003
Scopus:	2-s2.0-0021455429
РИНЦ:	22694464
Chemical Abstracts:	1984:498364
Chemical Abstracts (print):	101:98364
OpenAlex:	W2074994628
Sciact:	12294

Цитирование в БД:

БД	Цитирований
Scopus	42
OpenAlex	37

Альметрики: