Effects of the Interaction of Dispersed Metal Particles with the Support in Catalysts Prepared Using Organometallic Compounds. VI. Study of the State of Components in (Pd+Zr)/SiO2 Научная публикация
| Журнал |
Applied Catalysis
ISSN: 0166-9834 |
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| Вых. Данные | Год: 1990, Том: 63, Номер: 1, Страницы: 51-65 Страниц : 15 DOI: 10.1016/S0166-9834(00)81705-4 | ||
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Реферат:
Fourier transform infrared, X-ray photoelectron and extended X-ray absorption fine structure spectroscopy applied were to study the formation and state of components and forms of carbon monoxide adsorption with (Pd+Zr)/SiO2 catalysts obtained from organometallic precursors. Based on the results obtained, a model of active sites assuming direct interaction of highly dispersed palladium particles with surface zirconium ions is proposed. Taking into account the similarity of the adsorptive and catalytic properties of (Pd+Zr)/SiO2 and Pd/ZrO2 systems, which reveal the effects of a strong metal-support interaction (SMSI), the possibility of the application of this model to explain the mechanism of SMSI is discussed.
Библиографическая ссылка:
Ryndin Y.A.
, Alekseev O.S.
, Paukshtis E.A.
, Kalinkin A.V.
, Kochubey D.I.
Effects of the Interaction of Dispersed Metal Particles with the Support in Catalysts Prepared Using Organometallic Compounds. VI. Study of the State of Components in (Pd+Zr)/SiO2
Applied Catalysis. 1990. V.63. N1. P.51-65. DOI: 10.1016/S0166-9834(00)81705-4 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact
Effects of the Interaction of Dispersed Metal Particles with the Support in Catalysts Prepared Using Organometallic Compounds. VI. Study of the State of Components in (Pd+Zr)/SiO2
Applied Catalysis. 1990. V.63. N1. P.51-65. DOI: 10.1016/S0166-9834(00)81705-4 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact
Даты:
| Поступила в редакцию: | 28 июл. 1989 г. |
| Опубликована в печати: | 1 янв. 1990 г. |
| Опубликована online: | 2 окт. 2001 г. |
Идентификаторы БД:
| Web of science: | WOS:A1990DU74300004 |
| Scopus: | 2-s2.0-0025469524 |
| РИНЦ: | 31150845 |
| Chemical Abstracts: | 1990:559750 |
| Chemical Abstracts (print): | 113:159750 |
| OpenAlex: | W121134615 |
| Sciact: | 12268 |