Реферат: NMR imaging and spectroscopy techniques are applied to study flow and filtration of liquids, gases and granular solids in various geometries and to the in situ studies of the interplay of mass transport and catalytic reactions in porous media. In particular, quantitative spatially resolved maps of flow velocities of liquids and gases in the channels of monoliths have been obtained. A comparative study of the filtration of water and propane through model porous media has revealed that the dispersion coefficients for water are dominated by the holdup effects even in a bed of nonporous glass beads. Similar experiments performed with the gravity driven flow of liquid-containing fine solid particles through a porous bed have yielded the distributions of particle velocities for various flow rates. The NMR imaging technique was employed to visualize the propagation of autocatalytic waves for the Belousov–Zhabotinsky reaction carried out in a model porous medium. It was demonstrated that the wave propagation velocity decreases as the wave crosses the boundary between the bulk liquid and the flooded bead pack. The images detected during the catalytic hydrogenation of α-methylstyrene on a single catalyst pellet at elevated temperatures have revealed that the reaction and the accompanying phase transition alter the distribution of the liquid phase within the pellet.

Библиографическая ссылка: Koptyug I.V. , Lysova A.A. , Matveev A.V. , Parmon V.N. , Sagdeev R.Z.
NMR Imaging of Mass Transport Processes and Catalytic Reactions
Topics in Catalysis. 2005. V.32. N1-2. P.83-91. DOI: 10.1007/s11244-005-9256-1 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact

Даты:

Опубликована в печати:

1 февр. 2005 г.

Идентификаторы БД:

Web of science:	WOS:000226939900010
Scopus:	2-s2.0-13844276902
РИНЦ:	13485515
Chemical Abstracts:	2005:89739
Chemical Abstracts (print):	142:282198
OpenAlex:	W2090051635
Sciact:	11386

Цитирование в БД:

БД	Цитирований
Scopus	16
OpenAlex	14

Альметрики: