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Oscillations in the NO-CO Reaction on Pt(100): NO Decomposition on Island Boundaries Научная публикация

Журнал Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X
Вых. Данные Год: 2002, Том: 84, Номер: 3-4, Страницы: 147-152 Страниц : 6 DOI: 10.1023/A:1021462900861
Авторы Zhdanov Vladimir P. 1,2
Организации
1 Department of Applied Physics, Chalmers University of Technology, 412 96 Göteborg, Sweden
2 Boreskov Institute of Catalysis, Russian Academy of Sciences, Novosibirsk 630090, Russia
Реферат: We present the first Monte Carlo simulations of kinetic oscillations in heterogeneous catalytic reaction with one of the key reaction steps occurring on the boundaries between the islands formed due to adsorbate-induced surface restructuring. Specifically, we treat NO reduction by CO on the Pt(100) surface with NO decomposition on the interface between the “hex” and (1× 1) phases. For this scenario, in agreement with experiment, our model predicts damped oscillations with correlation between broad maxima in the CO2-formation rate and minima in the (1 × 1) area.
Библиографическая ссылка: Zhdanov V.P.
Oscillations in the NO-CO Reaction on Pt(100): NO Decomposition on Island Boundaries
Catalysis Letters. 2002. V.84. N3-4. P.147-152. DOI: 10.1023/A:1021462900861 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact
Даты:
Поступила в редакцию: 9 апр. 2002 г.
Принята к публикации: 15 авг. 2002 г.
Опубликована в печати: 1 дек. 2002 г.
Идентификаторы БД:
Web of science: WOS:000179774300003
Scopus: 2-s2.0-0036883418
РИНЦ: 13407089
Chemical Abstracts: 2002:943906
Chemical Abstracts (print): 138:242126
OpenAlex: W1511528647
Sciact: 9390
Цитирование в БД:
БД Цитирований
Scopus 7
OpenAlex 9
Альметрики: