Kinetic Aspects of the Structure-Gap Problem in Heterogeneous Catalysis Научная публикация
| Журнал |
Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X |
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| Вых. Данные | Год: 2002, Том: 81, Номер: 3-4, Страницы: 141-145 Страниц : 5 DOI: 10.1023/A:1016525022453 | ||||
| Авторы |
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| Организации |
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Реферат:
Analyzing one of the possible schemes of the NO–CO reaction occurring on nm-sized supported Rh or Pd particles, we show that, due to the purely kinetic effects related to the interplay of the reaction kinetics on the (111) and (100) facets, the activity of a catalyst particle may be appreciably higher than that calculated by using the conventional approximation based on the assumption that the facets operate independently. The dependence of the turnover reaction rate on the fraction of adsorption sites belonging to the (100) facet is found to exhibit a broad maximum at f ≃ 0.4.
Библиографическая ссылка:
Zhdanov V.P.
, Kasemo B.
Kinetic Aspects of the Structure-Gap Problem in Heterogeneous Catalysis
Catalysis Letters. 2002. V.81. N3-4. P.141-145. DOI: 10.1023/A:1016525022453 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact
Kinetic Aspects of the Structure-Gap Problem in Heterogeneous Catalysis
Catalysis Letters. 2002. V.81. N3-4. P.141-145. DOI: 10.1023/A:1016525022453 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact
Даты:
| Поступила в редакцию: | 20 нояб. 2001 г. |
| Принята к публикации: | 7 мар. 2002 г. |
| Опубликована в печати: | 1 авг. 2002 г. |
Идентификаторы БД:
| Web of science: | WOS:000176934300002 |
| Scopus: | 2-s2.0-0036668854 |
| РИНЦ: | 13408481 |
| Chemical Abstracts: | 2002:543890 |
| Chemical Abstracts (print): | 137:388371 |
| OpenAlex: | W1588897768 |
| Sciact: | 9389 |