A Kinetic Model of Standard Selective Catalytic Reduction of NO by NH3 on Two Sites Научная публикация
| Журнал |
Reaction Kinetics, Mechanisms and Catalysis
ISSN: 1878-5190 , E-ISSN: 1878-5204 |
||||
|---|---|---|---|---|---|
| Вых. Данные | Год: 2011, Том: 104, Номер: 2, Страницы: 267-272 Страниц : 6 DOI: 10.1007/s11144-011-0353-9 | ||||
| Авторы |
|
||||
| Организации |
|
Реферат:
Reduction of NO by NH3 in the presence of O2 may occur on single Fe or Cu atoms or dimers incorporated into the inner walls of zeolite. One of the likely schemes of this reaction implies the formation of N2 and H2O through the reaction of gas-phase NO and adsorbed NH3. The steady-state kinetics corresponding to this scheme was recently analyzed by the author assuming that the reaction runs on single metal atoms. In this work, the author presents a model including two metal atoms. Under the practically important conditions, the kinetics predicted by the one- and two-site models are demonstrated to be similar. In particular, both models allow one to interpret the apparent reaction orders observed experimentally.
Библиографическая ссылка:
Zhdanov V.P.
A Kinetic Model of Standard Selective Catalytic Reduction of NO by NH3 on Two Sites
Reaction Kinetics, Mechanisms and Catalysis. 2011. V.104. N2. P.267-272. DOI: 10.1007/s11144-011-0353-9 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact
A Kinetic Model of Standard Selective Catalytic Reduction of NO by NH3 on Two Sites
Reaction Kinetics, Mechanisms and Catalysis. 2011. V.104. N2. P.267-272. DOI: 10.1007/s11144-011-0353-9 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact
Даты:
| Поступила в редакцию: | 4 июн. 2011 г. |
| Принята к публикации: | 15 июл. 2011 г. |
| Опубликована online: | 2 авг. 2011 г. |
| Опубликована в печати: | 1 дек. 2011 г. |
Идентификаторы БД:
| Web of science: | WOS:000297169300003 |
| Scopus: | 2-s2.0-84877580048 |
| РИНЦ: | 20527946 |
| Chemical Abstracts: | 2011:1472992 |
| Chemical Abstracts (print): | 156:211143 |
| OpenAlex: | W4247426825 |
| Sciact: | 8101 |