A Kinetic Model of Standard Selective Catalytic Reduction of NO by NH3 on Single Sites

A Kinetic Model of Standard Selective Catalytic Reduction of NO by NH3 on Single Sites Научная публикация

Журнал

Reaction Kinetics, Mechanisms and Catalysis
ISSN: 1878-5190 , E-ISSN: 1878-5204

Вых. Данные

Год: 2011, Том: 103, Номер: 1, Страницы: 11-18 Страниц : 8 DOI: 10.1007/s11144-011-0285-4

Авторы

Zhdanov Vladimir P. ^1,2

Организации

1	Competence Centre for Catalysis, Chalmers University of Technology, 41296 Gothenburg, Sweden
2	Boreskov Institute of Catalysis, Russian Academy of Sciences, 630090 Novosibirsk, Russia

Reduction of NO by NH3 in the presence of O2 may occur on single Fe or Cu atoms or dimers incorporated into the inner walls of a zeolite. Although this process is of considerable intrinsic interest as an example of complex reactions running on single sites and is also important from the perspective of environmental chemistry, its mechanism is still open for debate. One of the likely schemes of the process implies the formation of N2 and H2O via the reaction of gas-phase NO and adsorbed NH3. The author presents a detailed analysis of the steady-state kinetics corresponding to this scheme. The model employed includes eleven elementary steps. The results obtained allow one to interpret the apparent reaction orders observed experimentally.

Zhdanov V.P.
A Kinetic Model of Standard Selective Catalytic Reduction of NO by NH3 on Single Sites
Reaction Kinetics, Mechanisms and Catalysis. 2011. V.103. N1. P.11-18. DOI: 10.1007/s11144-011-0285-4 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact

Поступила в редакцию:	24 сент. 2010 г.
Принята к публикации:	12 янв. 2011 г.
Опубликована online:	4 февр. 2011 г.
Опубликована в печати:	1 июн. 2011 г.

Web of science:	WOS:000290169600002
Scopus:	2-s2.0-79960041370
РИНЦ:	18058156
Chemical Abstracts:	2011:545470
Chemical Abstracts (print):	154:551516
OpenAlex:	W2114786728
Sciact:	8100

БД	Цитирований
Scopus	3
OpenAlex	3