Hydroformylation of 1-Hexene Catalyzed by Water Soluble CoCl2(TPPTS)2 in Biphasic Medium

Hydroformylation of 1-Hexene Catalyzed by Water Soluble CoCl2(TPPTS)2 in Biphasic Medium Научная публикация

Журнал

Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169

Вых. Данные

Год: 2004, Том: 211, Номер: 1-2, Страницы: 83-87 Страниц : 5 DOI: 10.1016/j.molcata.2003.10.021

Авторы

Parmar Dharmesh U. ¹ , Bajaj Hari C. ¹ , Jasra Raksh V. ¹ , Moroz B.M. ² , Likholobov V.A. ²

Организации

1	Silicates and Catalysis Discipline, Central Salt and Marine Chemicals Research Institute, G.B. Marg, Bhavnagar-364002, Gujarat, India
2	Boreskov Institute of Catalysis, Novosibrisk 630 090, Russia

CoCl2(TPPTS)2 catalyzed hydroformylation of 1-hexene was studied in an aqueous biphasic medium. The effect of temperature, pressure, and concentration of cobalt catalyst on the reaction was studied. At elevated temperatures and pressures, it gave >90% conversion with 68% selectivity for aldehyde and n/iso ratio of 3.0 for the aldehyde. Water soluble cobalt complex of tri(m-sulfophenyl)-phosphine (TPPTS) is found to be selective for aldehyde compared to alcohol during hydroformylation of 1-hexane at 100 °C temperature and 9 MPa pressure.

Parmar D.U. , Bajaj H.C. , Jasra R.V. , Moroz B.M. , Likholobov V.A.
Hydroformylation of 1-Hexene Catalyzed by Water Soluble CoCl2(TPPTS)2 in Biphasic Medium
Journal of Molecular Catalysis A: Chemical. 2004. V.211. N1-2. P.83-87. DOI: 10.1016/j.molcata.2003.10.021 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact

Поступила в редакцию:	9 июн. 2003 г.
Принята к публикации:	17 окт. 2003 г.
Опубликована online:	24 дек. 2003 г.
Опубликована в печати:	15 мар. 2004 г.

Web of science:	WOS:000188928600011
Scopus:	2-s2.0-0942289858
РИНЦ:	13449908
Chemical Abstracts:	2004:75070
Chemical Abstracts (print):	140:376994
OpenAlex:	W1988326602
Sciact:	7432

БД	Цитирований
Scopus	29
OpenAlex	25