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Cluster Molecular Modeling of Strong Interaction for VOx/TiO2 Supported Catalyst Научная публикация

Журнал Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169
Вых. Данные Год: 2002, Том: 178, Номер: 1-2, Страницы: 191-198 Страниц : 8 DOI: 10.1016/S1381-1169(01)00301-6
Авторы Kachurovskaya Nelly A. 1 , Mikheeva Emiliya P. 1 , Zhidomirov Georgii M. 1
Организации
1 Boreskov Institute of Catalysis, Russian Academy of Sciences, Prospekt Lavrentieva 5, Novosibirsk 630090, Russia
Реферат: Cluster molecular models of VOx/TiO2 catalytic system based on embedding process of V-ion in the anatase support were considered. Cluster structures of (0 0 1) anatase surface, containing one- and two-layer were constructed and isomorphous substitution of two Ti-ions on two V-ions were calculated. Comparison of the Brönsted acidic properties of V–OH group on the surface of V2O5 and supported VOx/TiO2 species showed that embedding procedure increases their acidic power and the influence of the second layer of the support is essentially important. Formation of ammonium ion under the adsorption of NH3 on supported and unsupported vanadium oxide catalyst was considered and discussed.
Библиографическая ссылка: Kachurovskaya N.A. , Mikheeva E.P. , Zhidomirov G.M.
Cluster Molecular Modeling of Strong Interaction for VOx/TiO2 Supported Catalyst
Journal of Molecular Catalysis A: Chemical. 2002. V.178. N1-2. P.191-198. DOI: 10.1016/S1381-1169(01)00301-6 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact
Даты:
Поступила в редакцию: 11 окт. 2000 г.
Принята к публикации: 25 июн. 2001 г.
Опубликована online: 28 дек. 2001 г.
Опубликована в печати: 23 янв. 2002 г.
Идентификаторы БД:
Web of science: WOS:000173274500023
Scopus: 2-s2.0-0037160269
РИНЦ: 13411198
Chemical Abstracts: 2002:6203
Chemical Abstracts (print): 136:91457
OpenAlex: W2151494077
Sciact: 7044
Цитирование в БД:
БД Цитирований
Scopus 39
OpenAlex 38
Альметрики: