In situ FTIR Study of the Kinetics of Formic Acid Decomposition on V-Ti Oxide Catalyst under Stationary and Non-Stationary Conditions. Determination of Kinetic Constants

In situ FTIR Study of the Kinetics of Formic Acid Decomposition on V-Ti Oxide Catalyst under Stationary and Non-Stationary Conditions. Determination of Kinetic Constants Научная публикация

Журнал

Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169

Вых. Данные

Год: 2009, Том: 312, Номер: 1-2, Страницы: 92-96 Страниц : 5 DOI: 10.1016/j.molcata.2009.07.022

Авторы

Ivanov E.A. ¹ , Popova G.Ya. ¹ , Chesalov Yu.A. ¹ , Andrushkevich T.V. ¹

Организации

1	Boreskov Institute of Catalysis, Prosp. Acad. Lavrentieva 5, Novosibirsk 630090, Russia

Decomposition of formic acid over V–Ti oxide catalyst under stationary and non-stationary conditions was studied by in situ IR spectroscopy at temperature range 50–150 °C. The kinetic scheme was shown to include the steps of reverse adsorption of formic acid and formate decomposition to CO. The rate constants and activation energies were estimated according to the proposed kinetic model. The kinetic model satisfactorily describes the experimental data under stationary and non-stationary conditions.

Ivanov E.A. , Popova G.Y. , Chesalov Y.A. , Andrushkevich T.V.
In situ FTIR Study of the Kinetics of Formic Acid Decomposition on V-Ti Oxide Catalyst under Stationary and Non-Stationary Conditions. Determination of Kinetic Constants
Journal of Molecular Catalysis A: Chemical. 2009. V.312. N1-2. P.92-96. DOI: 10.1016/j.molcata.2009.07.022 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact

Поступила в редакцию:	23 апр. 2009 г.
Принята к публикации:	10 июл. 2009 г.
Опубликована online:	14 авг. 2009 г.
Опубликована в печати:	1 окт. 2009 г.

Web of science:	WOS:000270627800013
Scopus:	2-s2.0-69949097284
РИНЦ:	15307655
Chemical Abstracts:	2009:1127609
Chemical Abstracts (print):	152:357550
OpenAlex:	W2048699835
Sciact:	2898

БД	Цитирований
Scopus	34
OpenAlex	32