Isomerization of α-Pinene Oxide Over Iron-Modified Zeolites | Sciact

Isomerization of α-Pinene Oxide Over Iron-Modified Zeolites Научная публикация

Конференция

15th Nordic Symposium on Catalysis
16-18 июн. 2012 , Mariehamn, Åland

Журнал

Topics in Catalysis
ISSN: 1022-5528 , E-ISSN: 1572-9028

Вых. Данные

Год: 2013, Том: 56, Номер: 9-10, Страницы: 696-713 Страниц : 18 DOI: 10.1007/s11244-013-0029-y

Авторы

Kumar Narendra ¹ , Maki-Arvela Paivi ¹ , Diaz Sara Faten ¹ , Aho Atte ¹ , Demidova Yulia ² , Linden Johan ¹ , Shepidchenko Anna ¹ , Tenhu Mikko ¹ , Salonen Jarno ¹ , Laukkanen Pekka ¹ , Lashkul Alexander ¹ , Dahl Johnny ¹ , Sinev Iliya ³ , Leino Anne-Riikka ⁴ , Kordas Krisztian ⁴ , Salmi Tapio ¹ , Murzin Dmitry Yu. ¹

Организации

1	Åbo Akademi University, Turku, Finland
2	Boreskov Institute of Catalysis, Novosibirsk, Russia
3	Ruhr-University Bochum, Bochum, Germany
4	University of Oulu, Oulu, Finland

Fe-modified mordenite, ferrierite, Y, ZSM-5, ZSM-12 and beta zeolite catalysts were prepared by solid state ion-exchange and conventional liquid phase ion-exchange methods from aqueous solutions. Sn- modified H-beta-300 zeolite catalyst was prepared by the later method. The characterization of proton form, Fe and Sn modified zeolites was carried out using X-ray powder diffraction, scanning electron microscopy, Mössbauer spectroscopy with magnetic measurements, transmission electron microscopy, nitrogen adsorption, X-ray absorption spectroscopy, X-ray photoelectron spectroscopy, inductively coupled plasma spectroscopy, thermo-gravimetric analysis and FTIR spectroscopy using pyridine as a probe molecule. Isomerization of α-pinene oxide over the Fe and Sn modified zeolite catalysts was carried out in the liquid phase using a batch-wise glass reactor. Formation of campholenic aldehyde and fencholenic aldehyde were observed to be influenced by the structure, acidity of zeolite and contents of Fe and Sn, reaction temperature and the catalysts pretreatment.

Kumar N. , Maki-Arvela P. , Diaz S.F. , Aho A. , Demidova Y. , Linden J. , Shepidchenko A. , Tenhu M. , Salonen J. , Laukkanen P. , Lashkul A. , Dahl J. , Sinev I. , Leino A-R. , Kordas K. , Salmi T. , Murzin D.Y.
Isomerization of α-Pinene Oxide Over Iron-Modified Zeolites
Topics in Catalysis. 2013. V.56. N9-10. P.696-713. DOI: 10.1007/s11244-013-0029-y WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact

Опубликована online:	19 апр. 2013 г.
Опубликована в печати:	1 июн. 2013 г.

Web of science:	WOS:000320500200024
Scopus:	2-s2.0-84879847517
РИНЦ:	20439578
Chemical Abstracts:	2013:634765
Chemical Abstracts (print):	159:8877
OpenAlex:	W2109052705
Sciact:	1242

БД	Цитирований
Scopus	37
OpenAlex	37