A Novel Method of the Synthesis of Molybdovanadophosphoric Heteropoly Acid Solutions Научная публикация
| Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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| Вых. Данные | Год: 2008, Том: 95, Номер: 1, Страницы: 21-28 Страниц : 8 DOI: 10.1007/s11144-008-5374-7 | ||
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| Организации |
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Реферат:
A novel eco-friendly method of the synthesis of aqueous solutions of the Keggintype Mo-V-P heteropoly acids H3+x PV x Mo12−x O40 (HPA-x) is proposed. At the first stage, V2O5 is dissolved in cooled H2O2 to form peroxyvanadic compounds, which spontaneously decompose to yield a H6V10O28 solution. The latter is stabilized by the addition of H3PO4 to yield a H9PV14O42 solution that is added to a boiling aqueous suspension of (H3PO4 + MoO3). This suspension is gradually evaporated producing the HPA-x solution. This safe and practically wasteless method holds much promise for the preparation of HPA-x solutions with x = 2–6.
Библиографическая ссылка:
Odyakov V.F.
, Zhizhina E.G.
A Novel Method of the Synthesis of Molybdovanadophosphoric Heteropoly Acid Solutions
Reaction Kinetics and Catalysis Letters. 2008. V.95. N1. P.21-28. DOI: 10.1007/s11144-008-5374-7 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact
A Novel Method of the Synthesis of Molybdovanadophosphoric Heteropoly Acid Solutions
Reaction Kinetics and Catalysis Letters. 2008. V.95. N1. P.21-28. DOI: 10.1007/s11144-008-5374-7 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact
Даты:
| Поступила в редакцию: | 30 июн. 2008 г. |
| Принята к публикации: | 9 июл. 2008 г. |
| Опубликована в печати: | 1 окт. 2008 г. |
| Опубликована online: | 17 дек. 2008 г. |
Идентификаторы БД:
| Web of science: | WOS:000260113900003 |
| Scopus: | 2-s2.0-57649242774 |
| РИНЦ: | 13580110 |
| Chemical Abstracts: | 2008:1314103 |
| Chemical Abstracts (print): | 150:291754 |
| OpenAlex: | W2074236220 |
| Sciact: | 18717 |