Activity of MoSe2/Al2O3 Catalysts in Decomposition of Thiophene and Selenophene Научная публикация
| Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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| Вых. Данные | Год: 2007, Том: 90, Номер: 1, Страницы: 167-177 Страниц : 11 DOI: 10.1007/s11144-007-5079-3 | ||
| Авторы |
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| Организации |
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Реферат:
The rate of thiophene decomposition was shown to be of the type of chalcogens used in catalysts MoX2/Al2O3, where X = S, Se. On the contrary, the rate of selenophene decomposition was shown to be higher on catalysts MoSe2 than that on MoS2. This observation suggests that the decomposition proceeds on anion vacancies. The decomposition of either thiophene over MoSe2 or selenophene over MoS2 results in the formation of partially substituted chalcogenides. At that, the molar ratios of the substituted chalcogen to Mo were shown to coincide in both cases. The fact that the rate of the thiophene decomposition does not depend on the degree of anion exchange indicates that the decomposition is not associated with hydrogenolysis.
Библиографическая ссылка:
Kochubey D.I.
, Rogov V.A.
, Babenko V.P.
Activity of MoSe2/Al2O3 Catalysts in Decomposition of Thiophene and Selenophene
Reaction Kinetics and Catalysis Letters. 2007. V.90. N1. P.167-177. DOI: 10.1007/s11144-007-5079-3 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact
Activity of MoSe2/Al2O3 Catalysts in Decomposition of Thiophene and Selenophene
Reaction Kinetics and Catalysis Letters. 2007. V.90. N1. P.167-177. DOI: 10.1007/s11144-007-5079-3 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact
Даты:
| Поступила в редакцию: | 2 нояб. 2006 г. |
| Принята к публикации: | 10 нояб. 2006 г. |
| Опубликована в печати: | 1 февр. 2007 г. |
Идентификаторы БД:
| Web of science: | WOS:000243972300021 |
| Scopus: | 2-s2.0-33846784868 |
| РИНЦ: | 13544705 |
| Chemical Abstracts: | 2007:128342 |
| Chemical Abstracts (print): | 146:358395 |
| OpenAlex: | W2329765356 |
| Sciact: | 18692 |